Reaction order/constant, time dependent pressure

AI Thread Summary
The discussion centers on determining the order of a reaction and the specific rate constant using pressure data over time. The reaction involves the decomposition of CH5NH2 into C2H4 and NH3, with total pressure measured at various time intervals. Initial pressure of 55 mm Hg indicates the starting amount of the reactant, and later pressures reflect the sum of reactants and products. Calculating partial pressures using stoichiometry is essential for solving the problem accurately. The conversation highlights the importance of understanding the relationship between pressure and concentration in chemical kinetics.
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This isn't a homework question per se, but it is from a (graduate) textbook. I'm not taking a course in this, but I've been trying to learn some basic chemical kinetics and couldn't find other problems like this one.

Homework Statement


The rate of the reaction

CH5NH2(g) -> C2

H4(g) + NH3(g) is measured by noting Ptotal as a function of time. At 500 degrees celsius, the following results were obtained:
Time (sec): 0 60 360 600 1200 1500
Ptotal (mm Hg): 55 60 79 89 102 105

a: Find the order of the reaction.
b: Find the specific rate constant.

Homework Equations



The Attempt at a Solution



At first, I thought that this was a straightforward question asking me to use the integrated rate equations and graphing to find k, but then I noticed that, although pressure can be substituted for concentration (I think?) in this case, what was measured isn't the decrease in reactant, but rather increase in product. However, I don't understand the importance of the pressure of 55 mm Hg at t=0. I suppose I can't just use the difference between two Pts as x, the decrease in reactant. It's been a while since I've taken general chemistry, so any help is appreciated.
 
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55 mmHg reflects initial amount of the substance that decomposes (there is some typo in the formula). Later observed pressure is sum of both reactants and products. You can calculate partial pressures using reaction stoichiometry (how many moles of each product per every mole of reactant decomposed?).

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methods
 
Borek said:
55 mmHg reflects initial amount of the substance that decomposes (there is some typo in the formula). Later observed pressure is sum of both reactants and products. You can calculate partial pressures using reaction stoichiometry (how many moles of each product per every mole of reactant decomposed?).

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chemical calculators - buffer calculator, concentration calculator
www.titrations.info - all about titration methods


Ah, thank you. I haven't done these kind of questions for a while, so thinking about calculating partial pressure didn't even occur to me until much later. So the 55 mm Hg at t=0 is the pressure of the sole reactant before the reaction starts? I'll try this again later today.
 
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