As ghwells says, the doppler effect is "raw data", something that relates to what signals you actually get back if you listen to a broadcast and/or bounce a radar or something similar off a moving object.
The relativity of simultaneity is something you can deduce from the doppler effect with a few modest auxiillary assumptions, namely that the doppler effect depends only on the relative velocity, and that the doppler effect doesn't vary with distance, and that there is no preferred direction in space - that it's "isotropic".
Part of the deduction process involves setting up the concept of a "frame of reference" - something that you add-on top of raw sensory data to assign events locations and times to account for signal propagation delays.
If you're interested in the details, you can find them in for example Bondi's "Relativity and common sense". I gather some newer books cover this as well - Mermin was mentioned as one of the authors, but I haven't read his treatment, I assume it's very similar to Bondi's treatment.