Schrodinger Equation: No Higher Powers of ψ

This property is important in quantum mechanics and is the reason why wave functions can be superimposed, giving rise to the concept of wave packets.In summary, the Schrödinger equation for a free particle is a linear differential equation in ψ, meaning that only first powers of ψ and its derivatives appear. This allows for the possibility of superposition and the formation of wave packets, making it a fundamental concept in quantum mechanics.
  • #1
logearav
338
0
ψ and its derivatives occur only linearly in the Schrodinger equation, that is, second or higher powers of these quantities do not appear in the equation.
Schrodinger equation for a free particle is
i[itex]\hbar[/itex]∂ψ(x,t)/∂t = (-[itex]\hbar[/itex]2/2m)(∂2ψ(x,t)/∂x2)
Here (∂2ψ(x,t)/∂x2) is second power of ψ. Then how can we justify the statement "second or higher powers of ψ do not appear"?
 
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  • #2
That's the second derivative. The statement "linear" means no terms like (dψ/dx)^2 or ψ^2 appear.
 
  • #3
To follow that up, the key issue with the equation being linear is that if two wave functions are possible solutions (like two plane waves in your example), then any linear superposition of them is also a solution. This gives us the concept of "wave packets", and is important in a lot of quantum mechanics.
 
  • #4
Thanks for your replies Matterwave and Ken G
 
  • #5
logearav said:
ψ and its derivatives occur only linearly in the Schrodinger equation, that is, second or higher powers of these quantities do not appear in the equation.
Schrodinger equation for a free particle is
i[itex]\hbar[/itex]∂ψ(x,t)/∂t = (-[itex]\hbar[/itex]2/2m)(∂2ψ(x,t)/∂x2)
Here (∂2ψ(x,t)/∂x2) is second power of ψ. Then how can we justify the statement "second or higher powers of ψ do not appear"?

The Schrödinger equation is a differential linear equation in ψ.

For a free particle it is

i[itex]\hbar[/itex]∂/∂t ψ = K ψ

Since it is linear this means that if ψ1 and ψ2 are solutions, then any linear combination ψT = c1ψ1 + c2ψ2 is a solution as well.
 

1. What is the Schrodinger Equation?

The Schrodinger Equation is a mathematical equation that describes how the wave function of a quantum system evolves over time. It was developed by Austrian physicist Erwin Schrodinger in 1926 and is a fundamental equation in quantum mechanics.

2. What does "No Higher Powers of ψ" mean in the Schrodinger Equation?

In the Schrodinger Equation, ψ represents the wave function of a quantum system. "No Higher Powers of ψ" means that the equation only includes terms up to the first power of ψ, and does not include any higher powers such as ψ² or ψ³.

3. Why are higher powers of ψ excluded from the Schrodinger Equation?

The exclusion of higher powers of ψ in the Schrodinger Equation is a fundamental principle in quantum mechanics known as the superposition principle. This principle states that the wave function of a quantum system can only be a linear combination of other wave functions, and cannot include higher powers of itself.

4. What does the Schrodinger Equation tell us about the behavior of quantum systems?

The Schrodinger Equation allows us to calculate the probability of finding a quantum system in a certain state at a given time. It also describes how the wave function of the system changes over time, allowing us to make predictions about the system's behavior.

5. How is the Schrodinger Equation used in practical applications?

The Schrodinger Equation is used in many practical applications, such as calculating the energy levels of atoms and molecules, simulating quantum systems in computers, and designing quantum technologies. It is also the basis for many other important equations in quantum mechanics, making it a crucial tool for understanding the behavior of quantum systems.

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