Solving E Extensive Parameter Relation: cE = E(cS, cV, cN)

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SUMMARY

The discussion clarifies the relationship between extensive parameters and the equation cE = E(cS, cV, cN), where E represents energy, S represents entropy, V represents volume, and N represents the number of particles. It establishes that extensive quantities are additive, meaning that if a system is scaled, the extensive properties scale proportionally. The example provided illustrates that for mono-atomic ideal gases, the internal energy U can be expressed as U = U' + U", reinforcing the concept that extensive properties do not depend on specific functional forms.

PREREQUISITES
  • Understanding of extensive and intensive properties in thermodynamics
  • Familiarity with the concepts of entropy (S), volume (V), and number of particles (N)
  • Basic knowledge of mono-atomic ideal gas behavior
  • Proficiency in mathematical relationships involving proportionality and additivity
NEXT STEPS
  • Study the principles of thermodynamic properties and their classifications
  • Explore the derivation of internal energy for mono-atomic ideal gases
  • Learn about the implications of scaling laws in thermodynamics
  • Investigate the role of constants in thermodynamic equations and their physical significance
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Students of thermodynamics, physicists, and engineers interested in understanding extensive properties and their applications in energy calculations.

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[SOLVED] extensive quantity

Homework Statement


My teacher said that E=E(S,V,N) implies that c E = E(cS,cV,cN) where c is some constant. The justification was that E is an extensive parameter. I know what an extensive parameter is (proportional to N), but I do not see how that relation follows.


Homework Equations





The Attempt at a Solution

 
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1. E, S, V, and N are extensive quantities.
2. You have a system with a certain S, V, and N, and you calculate the energy E.
3. I replace the system with one twice as big.
4. You can either double S, V, and N and recalculate or just double E, right? This statement is identical to your equation.
 


the proper definition of an extensive quantity is: if there is a system with extensive quanty X' and another system with X" then the two systems together has property X, with X=X'+X". (the property is additive). This is independent of the existence of a function X(a,b,c) where a b and c are also extensive quantities. For example take the internal energy of systems consisting of mono-atomic ideal gases with for helium U'=n'(3/2)RT' and for neon U"=n"(3/2)RT". (Hence U=U(n,T)). Now if we take the systems together U=U'+U" and n=n'+n", independent of the actual values of T'and T". (and we do not need the constant c)
U (=E) is and extensive quantity independent from the suggested function, that is actually non-existent for most systems.
 

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