Something that bugs me about concentration

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When removing 100 mL from a 500 mL bottle of vinegar containing 5% acetic acid, the concentration of acetic acid remains at 5% in both the removed portion and the remaining solution. Concentrations are consistent in a well-mixed solution, meaning that regardless of the volume taken out, the percentage of acetic acid does not change. This principle can be illustrated with a population analogy, where if 50% of a country's population is female, the same percentage applies to any subset of that population, such as a city.
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This may sound ridiculous to the elite here, but if I had a bottle with 500mL of vinegar where 5% was acetic acid. If I removed 100 mL will there still be 5% acetic acid there then?
 
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Hi Hitman123, welcome to PF!

Concentrations are relative quantities, so they do not change regardless of the volume (provided that the solution is uniform, or "well mixed"). So that 100 ml you remove will be 5% acetic acid, and the 400 ml left will be 5% acetic acid.

Think about it this way: if I tell you that 50% of a country's population is female, and ask you what percentage of the population of a given city in that country is female, what would you answer?
 
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