Specific heat capacity at constant pressure

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SUMMARY

The discussion clarifies the definition and calculation of specific heat capacity at constant pressure (c_P) and constant volume (c_V). It establishes that c_P incorporates both the change in internal energy (dU) and the work done (W) during gas expansion, leading to the formula c_P = (ΔU + W) / (mΔT). In contrast, c_V is defined solely by the change in internal energy, expressed as c_V = ΔU / (mΔT). The distinction between these two concepts is critical for understanding thermodynamic processes involving gases.

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v_pino
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I've read that:

specific heat capacity at constant pressure = dU-W / m. dT

dU = change in internal energy
W = work done
m = mass of gas
dT = change in temperature

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However, shouldn't the right hand side equate to specific heat capacity at constant VOLUME?

By saying that it is specific heat capacity at constant pressure, I thought we have already taken into account the energy used to expand the gas.
 
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Specific heat capacity at constant pressure, by definition, is

c_P=\frac{1}{m}\left(\frac{\partial H}{\partial T}\right)_P=\frac{1}{m}\left(\frac{\partial (U+PV)}{\partial T}\right)_P=\frac{1}{m}\left(\frac{\partial U}{\partial T}\right)_P+\frac{P}{m}\left(\frac{\partial V}{\partial T}\right)_P

If c_P is constant, we can integrate and get

c_P=\frac{\Delta U+W}{m\Delta T}

In contrast,

c_V=\frac{1}{m}\left(\frac{\partial U}{\partial T}\right)_V

and, if c_V is constant,

c_V=\frac{\Delta U}{m\Delta T}

Does this answer your question?
 

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