Statistical thermodynamics - mean energy of a nonlinear oscillator

In summary, the conversation involves a discussion of calculating the mean kinetic energy, mean potential energy, and mean total energy of a classical one-dimensional nonlinear oscillator in equilibrium with a heat bath at temperature T. It is not necessary to evaluate any integrals explicitly. Additionally, the conversation considers the mean potential energy of a classical one-dimensional oscillator with a small anharmonic contribution. The leading contribution of this term is discussed using the phase-space distribution function in thermal equilibrium.
  • #1
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Homework Statement



Consider a classical one-dimensional nonlinear oscillator whose energy is given by [itex]\epsilon[/itex]=[itex]\frac{p^{2}}{2m}[/itex]+a[itex]x^{4}[/itex]

where x,p, and m have their usual meanings; the paramater, a, is a constant

a) If the oscillator is in equilibrium with a heat bath at temperature T, calculate its mean kinetic energy, the mean potential energy, and mean total energy (it is not necessary to evaluate any integrals explicitly)

b) Consider a classical one-dimensional oscillator whose energy is given by [itex]\epsilon[/itex]= [itex]\frac{p^{2}}{2m}[/itex] + [itex]\frac{1}{2}[/itex]k[itex]x^{2}[/itex]+a[itex]x^{4}[/itex].

In this case the anharmonic contribution a[itex]x^{4}[/itex] is very small. What is the leading contribution of this term to the mean potential energy? (Recall that for small u, [itex]e^{u}[/itex]~ 1 + u

The Attempt at a Solution



This relates to information in Gould and Tobochnik Chapter 6 (statistical and thermal physics). I have no idea how to approach this problem, and any guidance or thought provoking questions to help me get started would be appreciated
 
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  • #2
First think about, what's the phase-space distribution function in thermal equilibrium! Then it's pretty easy to evalute the mean values (although the integrals for the potential energy for the [itex]x^4[/itex] are not doable in closed form with elementary functions).
 

1. What is statistical thermodynamics?

Statistical thermodynamics is a branch of thermodynamics that uses statistical methods to study the behavior of a large number of particles, such as molecules, in a system. It helps to understand the macroscopic properties of a system by analyzing the microscopic behavior of its constituent particles.

2. What is the mean energy of a nonlinear oscillator?

The mean energy of a nonlinear oscillator is the average energy of the system over a long period of time. It takes into account the fluctuations in energy that occur due to the nonlinear behavior of the oscillator. It is an important concept in statistical thermodynamics as it helps to predict the behavior of a system.

3. How is the mean energy of a nonlinear oscillator calculated?

The mean energy of a nonlinear oscillator can be calculated using the Boltzmann distribution, which takes into account the probabilities of different energy levels of the system. It also depends on the temperature and other thermodynamic variables of the system.

4. What is the significance of the mean energy in statistical thermodynamics?

The mean energy of a system is a measure of its average internal energy. In statistical thermodynamics, it helps to understand the behavior of a system, such as its heat capacity and entropy. It also plays a crucial role in predicting the equilibrium state and phase transitions of a system.

5. Can the mean energy of a nonlinear oscillator be experimentally measured?

Yes, the mean energy of a nonlinear oscillator can be experimentally measured using various techniques, such as calorimetry and spectroscopy. These methods involve measuring the changes in energy of the system and calculating the mean energy from the obtained data. However, it is important to note that the accuracy of the measurement may be affected by factors such as external disturbances and the complexity of the system.

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