Sulphur Residue: Burning Pure Sulphur

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Discussion Overview

The discussion revolves around the combustion of pure sulfur and the nature of the solid residue left after burning. It explores the implications of purity, potential impurities, and methods for testing sulfur purity, along with some observations about the physical properties of sulfur.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification

Main Points Raised

  • One participant states that burning pure sulfur results in sulfur dioxide gas, with possible trace amounts of sulfur trioxide, suggesting that any solid residue indicates impurities.
  • Another participant questions the purity of the sulfur, noting that it is claimed to be 99.98% pure and asks how to test this purity.
  • A participant describes methods for testing sulfur purity, including weighing the sulfur before and after burning to calculate the residue weight, and discusses potential impurities based on the form of sulfur (e.g., crystals vs. powder).
  • It is mentioned that impurities could include anticaking agents like talc or clay, depending on the sulfur's intended use.
  • A participant describes the physical appearance of the sulfur powder, indicating it was chunky and difficult to handle, which may suggest it lacked anticaking agents.

Areas of Agreement / Disagreement

Participants generally agree that solid residue indicates impurities in the sulfur, but there is no consensus on the specific nature of these impurities or the methods for testing purity.

Contextual Notes

The discussion does not resolve the specific types of impurities that may be present in the sulfur or the effectiveness of the proposed testing methods. There are also assumptions about the purity level and the form of sulfur that may affect the results.

JGM_14
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When you burn pure sulphur, what is the solid residue left behind?
I Know that sulphur dioxide is the gas that is left behind.
 
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If it is pure sulfur you are burning and complete combustion takes place you get entirely sulfur dioxide gas (with some trace amounts of sulfur trioxide). There is probably some impurity that is causing the solid residue.
 
The sulphur is suppose to be 99.98% pure but you can never be too sure, how do you test this?
 
The cool thing about sulphur when you melt it is that it looks like blood.
 
You test the purity of sulfur in a variety of ways, including burning it to see if there is any residue.

Weigh the sulfur before you burn it and the residue. Then calculate 1 - (residue weight)/(initial wt.). The difference should be greater than 0.9998 if it is on spec.


The most likely impurity will depend on the nature of the sulfur. Was the sulfur in the form of large crystals or "flowers" or was it a free-flowing powder? Sometimes powders have anticaking agents added to them like talc to keep them freely flowing. Is the sulfur used to dust plants? If so, the impurity might be talc or clay. If the sulfur was originally in the form of large flakes, it could be anything... even a dirty crucible.
 
It came in the form of powder that probibly did not have an anticaking agent in it because it was kinda chunky in the package and difficult to get out.
 

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