Temperature change in an isentropic flow of an ideal gas

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Discussion Overview

The discussion revolves around the definition and implications of isentropic processes in the flow of an ideal gas, particularly focusing on the apparent contradiction between reversibility and the presence of temperature gradients that suggest heat transfer. Participants explore the concepts of adiabatic and reversible processes in the context of compressible gas flow through nozzles.

Discussion Character

  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • Some participants express confusion regarding the definition of isentropic processes, noting that they imply both reversibility and adiabatic conditions.
  • There is a concern that the presence of a temperature gradient during gas flow suggests heat transfer within the gas, which contradicts the notion of reversibility.
  • Participants highlight that, according to the second principle of thermodynamics, heat transfer due to a temperature gradient is inherently irreversible.
  • One participant uses an analogy of balloons containing gas to illustrate adiabatic expansion and the lack of significant heat exchange, but questions remain about the implications of temperature gradients on reversibility.
  • Another participant agrees with the adiabatic nature of the process but reiterates the issue of spatial temperature gradients leading to irreversible heat transfer within the gas.
  • Clarifications are made regarding the lack of significant heat transfer between parts of the gas, even in the presence of temperature gradients.

Areas of Agreement / Disagreement

Participants generally agree on the definitions of adiabatic and isentropic processes but disagree on the implications of temperature gradients and their effect on reversibility. The discussion remains unresolved regarding the reconciliation of these concepts.

Contextual Notes

Participants express uncertainty about the assumptions underlying the definitions of reversibility and adiabatic processes, particularly in the context of compressible gas flow and temperature gradients.

citrouille
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I am a bit confused by the definition of an isentropic process in the flow of an ideal gas.

isentropic implies reversible & adiabatic.

for a process to be reversible, there are no losses to friction (viscosity in this case),
for a process to be adiabatic, there is no heat transfer with the surroundings.

That being said, when a compressible gas flows through a nozzle, there is a temperature change. When this happens, a temperature gradient occurs. Where there is a temperature gradient, heat transfer occurs within the gas. I was always taught that, according to the 2nd principle of thermodynamics, a heat transfer due to a temperature gradient (from hot -> cold areas) is irreversible...which is directly contradicting the definition of a reversible & adiabatic flow...

Hope this is a pertinent question...

Thanks a lot for any help.
 
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citrouille said:
I am a bit confused by the definition of an isentropic process in the flow of an ideal gas.

isentropic implies reversible & adiabatic.

for a process to be reversible, there are no losses to friction (viscosity in this case),
for a process to be adiabatic, there is no heat transfer with the surroundings.

That being said, when a compressible gas flows through a nozzle, there is a temperature change. When this happens, a temperature gradient occurs. Where there is a temperature gradient, heat transfer occurs within the gas. I was always taught that, according to the 2nd principle of thermodynamics, a heat transfer due to a temperature gradient (from hot -> cold areas) is irreversible...which is directly contradicting the definition of a reversible & adiabatic flow...

Hope this is a pertinent question...

Thanks a lot for any help.

Imagine a bunch of balloons containing gas. Imagine that they expand when they fly out of a window. The expansion of the gas cools the gas in the balloons. Yet, there is not any significant heat exchange between the balloons. That's because there's not enough time permitted for that exchange of heat to be significant. Thus, it is adiabatic.
 
kmarinas86 said:
Imagine a bunch of balloons containing gas. Imagine that they expand when they fly out of a window. The expansion of the gas cools the gas in the balloons. Yet, there is not any significant heat exchange between the balloons. That's because there's not enough time permitted for that exchange of heat to be significant. Thus, it is adiabatic.

I do not have a problem with the fact that the process is adiabatic (no heat transfer with the surroundings). My problem is with the fact that the transformation is reversible, and yet there is a spatial temperature gradient which would cause heat transfer within the gas (not with the surroundings). Heat transfer due to a temperature gradient within the gas is irreversible...maybe I'm thinking too much...sorry
 
citrouille said:
kmarinas86 said:
Imagine a bunch of balloons containing gas. Imagine that they expand when they fly out of a window. The expansion of the gas cools the gas in the balloons. Yet, there is not any significant heat exchange between the balloons. That's because there's not enough time permitted for that exchange of heat to be significant. Thus, it is adiabatic.

I do not have a problem with the fact that the process is adiabatic (no heat transfer with the surroundings). My problem is with the fact that the transformation is reversible, and yet there is a spatial temperature gradient which would cause heat transfer within the gas (not with the surroundings). Heat transfer due to a temperature gradient within the gas is irreversible...maybe I'm thinking too much...sorry

If you count the separate balloons as members of the same "gas", you can easily see how there is not significant transfer of heat, not even between parts of the gas.
 
kmarinas86 said:
If you count the separate balloons as members of the same "gas", you can easily see how there is not significant transfer of heat, not even between parts of the gas.

That makes more sense ! Thanks a lot for clearing that up.
 

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