Astronomy has the interesting practice that nothing ever gets re-defined. Hipparchus defined the magnitude scale almost 3000 more than 2000 years ago, and called the brightest stars 1st magnitude, the next brightest 2nd magnitude, and so on. So we are stuck with a magnitude scale that runs backwards - where brighter stars have a smaller magnitude than dimmer stars.
Population I and Population II were defined before anyone knew why they were different and that Population II came before Population I.