Thermodynamics: Proofs of work done on/by gas during adiabatic process

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Homework Help Overview

The discussion revolves around the work done on and by a gas during a quasistatic adiabatic process in thermodynamics. Participants are examining the mathematical expressions for work in this context and addressing potential errors in derivations related to these expressions.

Discussion Character

  • Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants are attempting to derive the work expressions for adiabatic processes and are questioning the signs in their calculations. There is a focus on understanding the relationships between the variables involved, such as pressure, volume, and the adiabatic index.

Discussion Status

Some participants have provided feedback on the derivations, indicating where sign errors may have occurred. There is an ongoing exploration of the relationships between the different expressions for work, with some participants confirming the validity of certain transformations.

Contextual Notes

Participants express confusion regarding the derivations and signs, indicating a struggle with the mathematical aspects of the problem. There is a sense of shared experience in dealing with similar foundational issues in thermodynamics.

Matty R
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Hello

I'm really confused with this and would appreciate any help.

Homework Statement



a) Show that the work done on a gas during a quasistatic adiabatic compression is given by:

W = \frac{P_f V_f - P_i V_i}{\gamma - 1}

b) Show that the work done by a gas during a quasistatic adiabatic compression is given by:

w = \frac{P_i V_i - P_f V_f}{\gamma - 1}


Homework Equations



w = -W
PV^{\gamma} = K


The Attempt at a Solution



a) dW = -PdV
P = KV^{- \gamma}
W = -K \left[\frac{V^{1- \gamma}}{1 - \gamma} \right]^{V_f} _{V_i}
W = - \frac{P_f V_f - P_i V_i}{1 - \gamma}
W = \frac{P_i V_i - P_f V_f}{\gamma - 1}

I don't understand where I've gone wrong.

b) w = -W
w = - \frac{P_i V_i - P_f V_f}{\gamma - 1}
w = \frac{P_f V_f - P_i V_i}{1 - \gamma}

I also get this answer if I derive w from:

dw = PdV

I've probably got a minus sign mixed up, or something like that, but I've been through the derivation so many times it's invading my dreams. Okay, maybe it isn't that bad, but I'm really struggling.
 
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Matty R said:
Hello

I'm really confused with this and would appreciate any help.

Homework Statement



a) Show that the work done on a gas during a quasistatic adiabatic compression is given by:

W = \frac{P_f V_f - P_i V_i}{\gamma - 1}


w = -W
PV^{\gamma} = K


The Attempt at a Solution



a) dW = -PdV
P = KV^{- \gamma}
W = -K \left[\frac{V^{1- \gamma}}{1 - \gamma} \right]^{V_f} _{V_i}
W = - \frac{P_f V_f - P_i V_i}{1 - \gamma}
W = \frac{P_i V_i - P_f V_f}{\gamma - 1}

I don't understand where I've gone wrong.


You have changed sign too many times:-p.
W = - \frac{P_f V_f - P_i V_i}{1 - \gamma}=\frac{P_f V_f - P_i V_i}{\gamma-1}
 
Thanks for the reply.

So, erm, is this true:

W = - \frac{P_f V_f - P_i V_i}{1 - \gamma}
= \frac{P_f V_f - P_i V_i}{\gamma-1}
= \frac{P_i V_i - P_f V_f}{1 - \gamma}
 
Matty R said:
So, erm, is this true:

W = - \frac{P_f V_f - P_i V_i}{1 - \gamma}
= \frac{P_f V_f - P_i V_i}{\gamma-1}
= \frac{P_i V_i - P_f V_f}{1 - \gamma}

Yes.

ehild
 
Thank you very much for your help.

I'm feeling quite embarrassed now, though most of the threads I've created here have been about really basic mistakes, so I should be used to it. :rolleyes:
 

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