How Does Vibration Relate to the Third Law of Thermodynamics?

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Discussion Overview

The discussion revolves around the relationship between vibration and the Third Law of Thermodynamics, with a focus on how these concepts might relate to quantum mechanics and string theory. Participants explore the implications of vibration in different states of matter and its connection to thermodynamic principles.

Discussion Character

  • Exploratory
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant questions the validity of the claim that everything vibrates and seeks clarification on its connection to the Third Law of Thermodynamics and quantum mechanics.
  • Another participant suggests that the discussion may relate to M Theory or String Theory, proposing that vibrating strings of energy exist at a very small scale, although this remains unproven.
  • A participant references Max Planck's improvements to the Third Law of Thermodynamics, noting that at absolute zero, entropy is zero, but quantum systems like harmonic oscillators exhibit nonzero zero-point energy.
  • One participant explains that temperature reflects the kinetic energy of molecules, asserting that solid objects vibrate due to constrained molecular motion, while expressing uncertainty about applying the same concept to gases.
  • Another participant challenges the notion of gas molecules vibrating, arguing that their random motion does not fit the definition of vibration as periodic motion.
  • The original poster expresses a preference for string theory in their essay, indicating a desire to ensure their understanding aligns with the speculative nature of the theory.

Areas of Agreement / Disagreement

Participants exhibit a mix of agreement and disagreement regarding the definitions and implications of vibration in different states of matter, particularly between solids and gases. The discussion remains unresolved on how these concepts definitively relate to the Third Law of Thermodynamics.

Contextual Notes

There are limitations in the discussion regarding the definitions of "vibration" and the assumptions underlying the relationship between molecular motion and thermodynamic principles. The exploration of string theory as a speculative framework also introduces uncertainty about its acceptance in the context of established physics.

Who May Find This Useful

This discussion may be useful for students and enthusiasts in physics, particularly those interested in thermodynamics, quantum mechanics, and theoretical frameworks like string theory.

SimonP
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Hello, I wonder if any of you would be kind enough to help a layman?
I seem to remember a friend once told me that everything vibrates, and that nothing would exist if it didn't vibrate. For starters is this correct, or have I remembered incorrectly? Also, what is he talking about? Someone has told me that it could be the Third Law of Thermodynamics, but my friend was doing Quantum Mechanics, so perhaps it's something else? Does anyone have a clue what I could be looking for, and if so do you have the ability to explain it to an idiot?

Sorry if I'm wasting your time, but I'm a Creative Music Technology student with a severe lack of knowledge in Physics, and I'd like to include some in an essay I'm currently writing.

Thanks guys!

Si
 
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I think you are looking for M Theory or look under String Theory.

Basically its not proven yet but its a mathematically viable theory - if that makes any sense. The String Theorists claim that there are 11 dimensions and that on a really-really-really small scale there are vibrating strings of energy in all the matter. Now this can't (yet at least) be proven because the size of those strings in the smallest particles of matter is soooooooooo small that we can't physically see it (not yet -but its fail safe to say not in my lifetime)

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You should check out this site and watch all the videos there:
http://www.pbs.org/wgbh/nova/elegant/program.html
 
Max Planck improved the initial (1909) formulation of Walter Nernst of the III-rd principle of thermodynamics saying that at 0K,the entropy of anybody is zero and similar,the thermodynamical coefficients go to zero as the temperature goes to 0.
That doen't mean that for every system the energya and entropy are null at 0K.The QM harmonical oscillator is an example of a system that has nonzero zero-point energy.Even the entropy for a system of QM harmonic oscillators (a.k.a.the phononic system) is not zero.That's a quantum effect and it cannot be accounted for by the classical principle of Nernst-Planck.

Daniel.
 
The answer to this depends on what you mean by vibrating.

Temperature is a measure of the kinetic energy of molecules, so every object which has a measurable temperature (this is one way of saying "everything") must have molecular motion. In a solid object, molecular motion is constrained to vibrations within the molecular structure. So in that sense all solid objects are vibrating.

I would be harder to say the same thing about a gas.
 
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Nope,Integral,the atoms are vibrating within the molecule and they are looked upon as quantum vibrating systems similar to atoms in the nodes of a crytaline structure.

Daniel.

PS.I don't see why u say it is harder to say about gas.Just becuse those molcules are at the same time moving around?What's that got to do with vibrating atoms and Morse potential,for example...??

EDIT: :smile:
 
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Semantics.

The reason that I say it is harder to describe a gas as "vibrating" is because I do not see the random motion of a gas molecule as a "vibration". To me a vibration is constrained to some form of periodic motion.

Thus my opening statement, what do you mean by vibration.
 
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Thanks for the help guys, although I'm still finding it kinda hard to get my head round. I reckon I'm going to go with String Theory, as I've already written about that in the essay, - I just wanted to make sure I hadn't grasped the wrong end of the stick. Besides, I like string theory, and it's a lot easier to understand being that it's speculation.

Thanks again!

Si
 

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