Time evolution of an expectation value

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Discussion Overview

The discussion revolves around the time evolution of the expectation value of an observable in quantum mechanics, specifically addressing the derivation of related equations and the implications of using natural units where ##\hbar = c = 1##. Participants explore the mathematical formalism and notation involved in this context.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Debate/contested

Main Points Raised

  • One participant expresses confusion about the derivation of the time evolution of an observable and the implications of setting ##\hbar = 1##.
  • Another suggests applying the product rule and the Schrödinger equation to derive the necessary expressions.
  • Concerns are raised about how the Hermitian nature of the Hamiltonian affects the derivation, particularly regarding the appearance of a factor of -i.
  • Some participants argue that using natural units simplifies calculations, while others prefer to retain constants for clarity and to illustrate limits in quantum mechanics.
  • There is a discussion about the notation used in quantum mechanics, particularly the representation of states and the implications of conjugation in bra-ket notation.
  • A participant questions whether the adjoint of the time derivative operator ##\partial_t## is defined in this context, leading to a clarification that it is not.

Areas of Agreement / Disagreement

Participants express differing views on the use of natural units versus retaining constants in equations. There is no consensus on the best approach to notation and derivation methods, and several points of confusion remain unresolved.

Contextual Notes

Some participants highlight limitations in understanding dimensional analysis and the implications of Hermitian operators, which may affect their interpretations of the equations discussed.

jaurandt
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Watching Dr. Susskind show how to find the time evolution of the average of an observable K, he writes:

241199


I can not for the life of me figure out he derived it, and he also did something which I found terribly annoying throughout which is set hbar to 1, so after steps you lose where the hbar goes. Can anyone help me figure out how this is derived?
 
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Apply on the left the product rule twice and use twice the Schrödinger equation ##i\hbar \partial_t \psi = \widehat H \psi##.
 
A. Neumaier said:
Apply on the left the product rule twice and use twice the Schrödinger equation ##i\hbar \partial_t \psi = \widehat H \psi##.

Thanks for your reply. That much I do understand, but what I don't understand is how doing that could ever produce a -i since H is obviously Hermitian and can act on either side...
 
Setting ##\hbar = c = 1## is standard unit convention in high-energy physics. It is just a matter of what unit system you choose to work in and natural units are by far the most convenient. You can always go back to a unit system where this is not the case by using dimensional analysis to insert the appropriate powers of ##\hbar## and ##c##.
 
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jaurandt said:
Thanks for your reply. That much I do understand, but what I don't understand is how doing that could ever produce a -i since H is obviously Hermitian and can act on either side...
But bras are conjugated, hence on the bra side, ##1/i=-i## becomes ##i##.
 
A. Neumaier said:
But bras are conjugated, hence on the bra side, ##1/i=-i## becomes ##i##.

So I am wrong in saying
(i)(hbar)d/dt<psi| = <psi|H ? I'm sorry I'm brand new to this forum and I don't know how to create the symbols.
 
Orodruin said:
Setting ##\hbar = c = 1## is standard unit convention in high-energy physics. It is just a matter of what unit system you choose to work in and natural units are by far the most convenient. You can always go back to a unit system where this is not the case by using dimensional analysis to insert the appropriate powers of ##\hbar## and ##c##.

Maybe it'll come more naturally to me eventually, but dimensional analysis seems to confuse me more than just leaving in the constants.
 
jaurandt said:
I don't know how to create the symbols.
Use standard latex but with two hash signs in place of single dollars (but keep double dollars). You can look at how I did it by clicking on the reply button of my post.
jaurandt said:
So I am wrong in saying(i)(hbar)d/dt<psi| = <psi|H ?
Yes. It is easiest to see if you use linear algebra notation, i.e., ##\psi=|\psi\rangle## (viewed as a column vector) and ##\psi^*=\langle\psi|## (viewed as the conjugate transposed row vector). Then $$i\hbar \partial_t \psi^*=-(i\hbar \partial_t \psi)^*=-(H\psi)^*=-\psi^*H.$$
 
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jaurandt said:
Maybe it'll come more naturally to me eventually, but dimensional analysis seems to confuse me more than just leaving in the constants.
After getting used to it, leaving the constants will just annoy you to the extreme as they add nothing of value to the physics and just act to obscure the mathematical relationships.
 
  • #10
Orodruin said:
After getting used to it, leaving the constants will just annoy you to the extreme as they add nothing of value to the physics and just act to obscure the mathematical relationships.
I don't agree. After 28 years of doing quantum mechanics I still like to write them each time (and am pleased if others do so, too). It displays the classical limit ##\hbar\to 0## and the nonrelativistic limit ##c^{-1}\to 0## very naturally. Writing ##\iota:=i/\hbar## and ##x_0=ct## in the formulas is almost as easy as writing ##i## and ##x_0=t## preserves the units.
 
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  • #11
A. Neumaier said:
I don't agree. After 28 years of doing quantum mechanics I still like to write them each time (and am pleased if others do so, too). It displays the classical limit ##\hbar\to 0## and the nonrelativistic limit ##c^{-1}\to 0## very naturally. Writing ##\iota:=i/\hbar## and ##x_0=ct## in the formulas is almost as easy as writing ##i## and ##x_0=t## preserves the units.
To each his (or her) own. To me, it is just clutter. Typically the non-relativistic and classical limits can be considered in other ways that do not involve ##c## or ##\hbar## and are more physical. Using ##c## or ##\hbar## is just a proxy.
 
  • #12
A. Neumaier said:
Use standard latex but with two hash signs in place of single dollars (but keep double dollars). You can look at how I did it by clicking on the reply button of my post.

Yes. It is easiest to see if you use linear algebra notation, i.e., ##\psi=|\psi\rangle## (viewed as a column vector) and ##\psi^*=\langle\psi|## (viewed as the conjugate transposed row vector). Then $$i\hbar \partial_t \psi^*=-(i\hbar \partial_t \psi)^*=-(H\psi)^*=-\psi^*H.$$

First of all, I agree with your most recent posts about the constants. And I just started my own course of study on QM about 2 months ago. Very rigorously I may add, as I spend almost all of my time doing it.

Second, your math implies that the adjoint of $$\partial_t$$ is $$\partial_t$$

Is this correct? Basically, I just wasn't conjugating i for the bra form? In other words

H|psi> = (i)(hbar)(d/dt)|psi>

Corresponds to

<psi|H = <psi|(d/dt)(hbar)(-i)

Is this correct?
 
  • #13
jaurandt said:
Your math implies that the adjoint of $$\partial_t$$ is $$\partial_t$$

Is this correct?
No. ##\partial_t ## is not an operator acting on the Hilbert space but on the t-dependence of the state. Its adjoint is not defined in this context.
 
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