We can measure the position of the electron and find it on one side of the dielectric barrier, and then measure its position again at some later time and find it on the other side of the barrier.
If the electron behaved like a classical object (maybe it's like a grain of sand, except way smaller?) then we would be justified in saying that at some in-between time the electron was somewhere in the middle of the space occupied by the dielectric - how could it get from one side to the other without passing through the space in between?
But the electron does not behave like a classical object. It's a quantum object (the word "particle", implying something like a small grain of sand is an unfortunate historical accident) and according to the standard mathematical formalism of quantum mechanics, it has no position between measurements. That's "has no", not "somewhere, but we're not sure where". Asking about whether it occupies the space or not is like asking about your lap when you're standing up - neither yes nor no but just plain undefined.