Understanding Infrared Spectroscopy: Analysis of a Recorded Spectrum

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SUMMARY

The discussion focuses on the analysis of a recorded infrared spectrum where the user, Alain, is attempting to identify a gas species overlapping with CO2. Alain utilizes a 35m borosilicate gas cell and corrects the spectral data using reference gases H2 6.0 and He 6.0. The measurements are conducted at a constant pressure of 1000 mbar and temperature of 320 K. Notably, this spectrum is part of a series of ten samples, with the presence of 340 ppm Ethane, 14 ppm Methane, and traces of other hydrocarbons.

PREREQUISITES
  • Understanding of infrared spectroscopy principles
  • Familiarity with gas cell design and operation
  • Knowledge of spectral data correction techniques
  • Experience with gas composition analysis
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  • Research methods for correcting spectral data using reference gases
  • Explore the characteristics of borosilicate gas cells in spectroscopy
  • Learn about the identification of gas species in infrared spectra
  • Investigate the effects of pressure and temperature on spectral measurements
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Researchers and analysts in the field of spectroscopy, environmental scientists, and anyone involved in gas composition analysis and quality testing of gas samples.

Alain Ferbere
I do attach a plot (pdf and Matlab) of a recorded spectrum where I do not manage to find the gas specie overlapping CO2

Could you help me?

Best Alain
 

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One question I have is if you had the gas in some kind of glass container, did you correct your data for spectral runs with the glass, with and without the gas inside?
 
Charles Link said:
One question I have is if you had the gas in some kind of glass container, did you correct your data for spectral runs with the glass, with and without the gas inside?
Yes, I am using a 35m gas cell of borosilicate and I am corrected the data by using different reference gases (H2 6.0 and He 6.0). This recorded spectrum is only one of 10 different spectra from different samples collected for quality tests. I am keeping the pressure and the temperature constant at respectively 1000 mbar and 320 K during the measurements. All other samples, from various locations (H2 storage facilities) are not showing this special absorbance and it's the first time I have observed this absorbance feature. The other species present in this sample are 340 ppm Ethane, 14 ppm Methane and traces of Propane, IsoButane n-Butane and Ethanol. Regards, Alain
 

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