The direction of the electric dipole moment vector is defined from the negative charge to the positive charge primarily by convention, ensuring consistency across physics. This convention helps clarify the relationship between electric fields and polarization. The polarization field P, which is the sum of electric dipole moments, interacts with electric fields through specific equations, leading to some complexities in understanding the total electric field. Notably, the divergence of P relates to bound charge density, contrasting with free charge density. Overall, these conventions and relationships are crucial for accurately describing electric dipole behavior in fields.