I'll try to explain. Neutrons have a location in space, given by the coordinates ##(x,y,z)## or vector ##\vec{r}##, and a direction of travel, given by ##\vec{\Omega}##.
At the same point in space, you can have neutrons moving in direction ##\Omega_1## or ##\Omega_2## (i.e. different angular fluxes, but at the same point in space).
##\Omega## is a unit vector because it is a direction, and does not have a magnitude.
Note that in the Rouben notes, ##r## is not shown as a vector, but it is.
To find reaction rates, or to reduce to the diffusion equation, we want the total flux at a point in space summed over all angles.
This is called the "scalar flux", and it is just the angular flux summed over all directions.
This is the equation on page 5 of the Rouben notes. We are calculating the scalar flux by integrating the angular flux over all directions.
$$ \phi(r,E)=\int_{\Omega} \phi(r,E,\Omega) \, d\Omega$$
Note that the quantity on the left hand side is the scalar flux (no angular dependence) and the quantity in the integral is the angular flux (with an angular dependence).
Now, it becomes a math problem. Since ##\Omega## is a vector, you have to transform it into a coordinate system, either ##(x,y,z)## or ##(r,\theta,\phi)##, or some other system. There are different ways of doing this, and the Wolfram site gives several different coordinate systems in use.
On page 6 of the Rouben notes, he uses the coordinate system with ##\alpha## and ##\theta##.
Integrating over the solid angle is a calculus problem, not a nuclear engineering problem.
Does this answer your question?