Using Reciprocal to Determine Miller Indices

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SUMMARY

The discussion focuses on determining Miller indices using reciprocal lattice vectors for a Body-Centered Cubic (BCC) lattice. The reciprocal space basis vectors are defined as b1 = (2π/a)(x + y), b2 = (2π/a)(z + y), and b3 = (2π/a)(x + z). The confusion arises regarding the shortest reciprocal lattice vector, which is identified as having the Miller index (110) rather than the expected {111}. The relationship between cubic and primitive Miller indices is emphasized as crucial for understanding this discrepancy.

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Chillguy
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If we know the reciprocal space basis of a BCC lattice b_1=\frac{2\pi}{a}(\vec{x}+\vec{y}),b_2=\frac{2\pi}{a}(\vec{z}+\vec{y}),b_3=\frac{2\pi}{a}(\vec{x}+\vec{z}) how do we go about finding the shortest reciprocal lattice vector and its corresponding miller index?

To me all the constants in from of all reciprocal vectors are the same so the corresponding miller index should be {111} but it is apparently supposed to be ({110}). I conceptually can't make sense of this and any help would be appreciated.
 
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What you have written are the primitive basis vectors for the reciprocal lattice. For cubic materials one generally uses the conventional cubic unit cell. The corresponding reciprocal lattice unit cell is also cubit and has the basis vectors

a*=2pi/a x, b*=2pi/a x, c*=2pi/a z.

A reciprocal lattice vector is then G_HKL = H a* + K b* + L c*

Try to work out the relation between HKL_cubic and HKL_primitive, and then see what the HKL_cubic of, say, (100)_primitive, (110)_primitive and (111)_primitive are.
 

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