What are the common atomic radii used for chemical pictures?

AI Thread Summary
Common atomic radii used in chemical illustrations vary, with no strict rules governing their application. The choice often depends on the intended purpose of the images. For general representations, consistency is key rather than strict adherence to scientific accuracy. Many software programs default to using half the covalent radii for ball-and-stick models, as van der Waals radii can appear overly bulky. Space-filling models typically utilize full covalent radii or slightly larger. It's emphasized that the spheres in these illustrations are primarily for structural representation, lacking significant physical meaning. For more detailed insights into orbitals, bonding, or electron densities, different plotting methods should be employed instead of relying solely on ball-and-stick models.
somasimple
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Hi all,

What are the common atomic radii that are used for drawing chemical pictures?

Is it the ionic or calculated or?

Thanks.
 
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Whatever, as far as I am aware there are no set rules. There is some obvious logic that you can apply, but as long as your pictures are not drawn to be a scientific tool (like DNA models built by Watson and Crick) you don't have to pay too much attention to it. Just be consistent.
 
My program uses (for its default ball-and-stick mode) half the covalent radii. (vdW radii look a bit too chunky). Most programs use something similar. (To the extent I sometimes see papers with images that might have been made with my program, but I can't be sure) "Spacefill" models would be around the full covalent radius, or slightly larger.

It's not like the spheres in these pictures have much in the way of physical meaning; you're only drawing the structure.
If you want to say something about orbitals or bonding or electron densities, then that's what you plot, not ball-and-stick models.
 
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