Electrons jump into holes due to the uncertainty principle, which allows for a probability that an electron can change states and occupy a hole. Holes are considered positively charged because they attract electrons, but this characterization is supported by experimental evidence such as the Hall effect in n-type and p-type semiconductors. The movement of electrons into holes results in the effective movement of the holes themselves. This process illustrates the dynamic nature of electron behavior in semiconductors. Understanding these concepts is essential for grasping semiconductor physics.