What does this symbol mean in a chemical equation?

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The discussion revolves around the interpretation of a chemical equation featuring the symbol "↓," which indicates that calcium carbonate (CaCO3) precipitates out of solution. The equation presented is Ca(OH)2(aq) + Na2CO3(s) → CaCO3 ↓ + 2 NaOH(aq). Participants clarify that the "↓" symbol signifies the formation of a solid precipitate, similar to how "↑" indicates the evolution of gas in another reaction. It is noted that the states of the reagents (aqueous, solid, gas) make the arrow symbols somewhat redundant. The conversation concludes with the understanding that the reaction can yield sodium hydroxide (NaOH) if the precipitated CaCO3 is removed, as it is not chemically bonded to NaOH.
thebosonbreaker
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I recently stumbled across a chemical equation, which had a symbol I have never seen before.
If anyone can tell me what this symbol means, I would be very grateful.

Here's the equation:
Ca(OH)2(aq) + Na2CO3(s) → CaCO3 ↓ + 2 NaOH(aq)

...and I'd like to know what the "↓" symbol means.

Many thanks in advance.
 
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It means that CaCO3 precipitates and is not in solution.
 
Just like ↑ in

CaCO3 + 2HCl → CO2↑ + CaCl2 + H2O

means evolving gas.

Note that is the reagent states are given (as (g), (aq), (s)) these arrows are typically redundant.
 
Ahh! That does make sense.

So that would mean that this reaction could be used to produce just NaOH if the CaCO3 was removed (which the arrow states would be possible because the CaCO3 is not chemically bonded in any way with the NaOH, and could therefore be removed.)

Thanks a lot!
 
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