Rotational emissions occur when a molecule transitions to a lower spin state, releasing energy as low-energy photons in the micro and radio frequency range. This process is governed by quantum mechanics and is distinct from vibrational emissions, which emit infrared radiation. The discussion seeks methods to intentionally lower a molecule's spin state to induce rotational emissions, exploring potential protocols involving magnets or voltage changes. Understanding these mechanisms could enhance applications in astronomy and microscopy. Further insights or clarifications on these methods are welcomed.