What Indicators Are Best for Titration of HNO3 with NaCN and LiOH with HNO2?

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For the titration of HNO3 with NaCN, a suitable indicator must be chosen based on the pH at the equivalence point. The discussion emphasizes the need to calculate the pH of the resulting salt solution to identify the appropriate indicator. In the case of LiOH titrated with HNO2, the hydrolysis of NO2^- is relevant, with its Ka value being 5.1E-4, indicating a pH around 8-10 at the equivalence point. The challenge lies in selecting an indicator that transitions within this pH range. Proper calculations of the pH at the equivalence point are crucial for determining the correct indicators for both titrations.
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Homework Statement


Select a suitable indicator for each of the following titrations:
HNO3 added to NaCN

LiOH added to HNO2

Homework Equations


all i know is Ka(HIn)=[H3O] at transition point and pKa(HIn)=pH at transition point



The Attempt at a Solution


the book I have is really skimpy on this, and is has no other information, or even an example.

For LiOH + HNO2 <----> H20 + LiNO2
ic that Li doesn't hydrolyze and NO2 does. the ka for NO2 is 5.1E-4 which should also be the Ka then I -log(5.1E-4) and I get the wrong answer? The answer should be an indicator with a pH range around 8-10. I don't get it, can someone please help me?
 
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