To calculate the pH of a 5.525g HClO solution in 100mL, one must consider that HClO is a weak acid and utilize its dissociation constant. The discussion also touches on a separate problem involving the pH of a solution made by dissolving 0.012g LiOH in 50mL, where participants clarify the concentration of hydroxide ions and the correct pH calculation. It is emphasized that LiOH is a strong base, leading to full dissociation and a straightforward calculation of pH. Participants engage in correcting each other's calculations and understanding the relationships between hydronium and hydroxide concentrations. Ultimately, the conversation highlights the importance of accurate concentration values and the proper application of pH formulas.