What is the relationship between refractive index and pressure in gases?

AI Thread Summary
The refractive index of gases, which is close to 1, is shown to depend on pressure according to the equation n_r = 1 + K × p. The discussion highlights the importance of the Clausius-Mossotti equation and the ideal gas law in understanding this relationship. Participants emphasize the need to correctly interpret the symbols in these equations, particularly the density's dependence on pressure. There is some confusion regarding the application of the Clausius equation, but it is ultimately deemed necessary for solving the problem. Understanding the relationship between density and pressure is crucial for deriving the refractive index's dependence on pressure.
Aeon
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Dependence of refractive index on pressure

Homework Statement


Show that, in a gas (for which the refractive index is close to 1), the refractive index depends on the pressure as n_r = 1+ K\times p, and find the value of K.

Homework Equations



n_r = 1+ K\times p
Clausius-Mossotti equation: \frac{\epsilon_r - 1}{\epsilon_r + 2} = \frac{\rho N_a \alpha}{3M\epsilon_0}
\alpha^'\ = \frac{\alpha}{4\pi \epsilon_0}
n_r = \epsilon_r^{1/2}

The Attempt at a Solution



Any help to get me started, conceptual or mathematical, will be appreciated!

PS: I think I have posted this question in the right forum now. I had posted it in Advanced Physics before... I would have deleted my other post, but I can't.
 
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Which quantity on the right-hand side depends on the pressure p?

ehild
 
Supposing you're talking about the Clausius equation, I would say \frac{\rho}{M} = \frac{1}{V_m} depends on the pressure (inversely to how it behaves in phase diagrams).
 
The problem confuses me. I don't understand how I can go from the Clausius equation to <br /> n_r = 1+ K\times p<br />
 
Think of the ideal gas law. What is the relation between density and pressure?

ehild
 
i got confused
 
\rho = \frac{mp}{nRT}

To be honest, I'm starting to think I don't even NEED the Clausius equation to solve this problem...

Do I?
 
You do. Check the ideal gas law. It is wrong as you wrote it.
The symbol n in the ideal gas low means number of moles, n= mass/molar mass. And look after the meaning of the symbols in the Clausius equation.

ehild
 
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