What is the Volume of a 50g Oxygen Gas Sample at 1.20 atm and 27°C?

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Discussion Overview

The discussion revolves around calculating the volume of a 50g sample of oxygen gas under specific conditions of pressure and temperature, utilizing the Ideal Gas Law and related gas properties. It includes attempts at solutions, unit conversions, and considerations of gas behavior in different scenarios.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Technical explanation

Main Points Raised

  • One participant presents a method using density derived from pressure and temperature to calculate volume, arriving at a value of 1.03 x 10-3 m3.
  • Another participant suggests using the Ideal Gas Law (PV = nRT) as a hint for solving the problem.
  • A subsequent calculation attempts to find volume using the Ideal Gas Law, leading to a proposed volume of 6509 L, which is questioned by others.
  • Participants point out that oxygen is a diatomic gas (O2) and emphasize the importance of unit consistency, particularly regarding the gas constant.
  • One participant recalculates the volume using the correct gas constant and finds a volume of 32.09 L, which is later confirmed as correct by another participant.
  • A new question is introduced regarding the equilibrium conditions and mass of desublimed solid when gas from one vessel is released into a vacuum state in another vessel.

Areas of Agreement / Disagreement

There is no consensus on the initial volume calculation using the Ideal Gas Law, as participants provide differing results and corrections. The later calculation of 32.09 L appears to gain agreement, but the new question about the equilibrium conditions introduces further complexity and uncertainty.

Contextual Notes

Participants express uncertainty regarding unit conversions and the implications of gas behavior under varying conditions, particularly in the context of the new question about desublimation and equilibrium.

Who May Find This Useful

Students and enthusiasts in chemistry and physics, particularly those interested in gas laws, thermodynamics, and related calculations in experimental setups.

Quincy
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Homework Statement


What is the volume of a sample of oxygen gas has a mass of 50 grams and is under pressure of 1.20 atm at 27 degrees celsius?

The Attempt at a Solution



Density = Pressure(in pascals)/(specific gas constant * Temperature (in kelvins))

1 atm = 101,325 pascals ~ 1.2 atm = 121,590 pascals
27oCelsius = 300.15 K

Density = (121,590 pascals)/(8.314 * 300.15 K) = 48.72 kg/m3 = 48,720 g/m3

48,720 g/m3 = 50 g/V ~ V = 1.03 x 10-3 m3
 
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Hint: Ideal Gas Law (PV = nRT)
 
So... (1.2 atm)(V) = (3.13 mol)(8.314)(300.15 K) ~ V = 6509 L??
 
Not quite --
1) Oxygen is a diatomic gas (O2)
2) Check your units -- your gas constant (and consequently the volume) is off by (about) two orders of magnitude!
_For your units, the gas constant is approximately 0.0821 L*atm/(K*mol)
 
(1.2 atm)(V) = (1.56 mol)(0.0821)(300.15 K) ~ V = 32.09 L?
 
Quincy said:
(1.2 atm)(V) = (1.56 mol)(0.0821)(300.15 K) ~ V = 32.09 L?
yes, that is correct
 
Hi, can someone please help me...its quite urgent...I have two vessels, one has capacity of 0.5l and the other 0.15l. The 0.15l is in a vacuum state held constantly at -80C and the 0.5l vessel is at 50mbar at room temperature (20C). I have gas in the 0.5l vessel...I then open the valve and release the gas to the vacuum upon which it immediately desublimes.. until it reaches equilibrium state and then i close the valve and take the smaller vessel away. What conditions hold at equilibrium? and how do I find the mass of desublimed solid?
 

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