What kind of phosphate is present in fertilizers?, some say that the

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The discussion centers on the types of phosphates used in fertilizers, primarily focusing on orthophosphate and its prevalence. While some participants assert that orthophosphate is the main form used, others highlight the complexity of phosphate types in fertilizers. Historically, "superphosphate," a combination of gypsum and monocalcium phosphate, was common, but the industry has largely transitioned to "triple superphosphate," produced by treating insoluble calcium phosphate with phosphoric acid. Both superphosphate and triple superphosphate yield chemically similar products, specifically Ca(H2PO4)2. Additionally, ammonium phosphate is mentioned as another variant. A participant notes a correlation between the shift to triple superphosphate and lawn issues in San Antonio, suggesting a potential link to the phosphate type, although this claim remains debated. The conversation emphasizes the diversity of phosphate sources in fertilizers and the implications for agricultural practices.
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What kind of phosphate is present in fertilizers?, some say that the orthophosphate is the one mostly used in fertilizers however some state otherwise, hoping you guys have the answer :)
 
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They used to put "superphosphate" in fertilizer, which is a mixture of gypsum and monocalcium phosphate but nowadays they just treat insoluble calcium phosphate (Ca3(PO4)2) with phosphoric acid instead of sulfuric acid and make something identical without the gypsum and call it "triple superphosphate". Both products are chemically Ca(H2PO4)2. I've seen ammonium phosphate used as well. There is no single type of phosphate used (ortho or poly) but most is ortho I believe.

http://www.extension.umn.edu/distribution/cropsystems/DC6288.html

My buddy Malcolm Beck has been watching the phosphate market for some time and he noticed that when the industry switched over to triple superphosphate the lawn problems began in San Antonio. He attributes it to the type of phosphate used but I'm unconvinced. I guess you could just add gypsum to regular fertilizer and make your own "super".
http://www.malcolmbeck.com/articles/phosphates-probemsandsolutions.htm
 
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