Iron is less effective than lead for blocking and absorbing radiation due to its higher radiation length, making lead superior in density and mass. Specifically, lead has a radiation length of 6.37 g cm-2, while iron's is 13.84 g cm-2, indicating lead's greater efficiency against high photon energies, particularly over 100 keV. For low-energy photons, the effectiveness of both materials varies based on the specific energy levels involved. Overall, lead is the preferred choice for radiation shielding, especially for X-rays and gamma radiation. Understanding these differences is crucial for selecting appropriate materials for radiation protection.