Photons scatter at angles other than 0 or 180 degrees due to the Heisenberg Uncertainty Principle, which implies that while a photon has a defined momentum, its position is uncertain. This uncertainty leads to varying impact parameters, resulting in a spectrum of scattering angles. The scattering process can be described classically by Thomson scattering and relativistically by Compton scattering, with both methods yielding similar results for photon energies up to about 100 keV. The conservation of energy and momentum in multiple planes is crucial for understanding the kinematics of the scattering process. Overall, the complexity of photon-electron scattering is rooted in quantum mechanics and the principles governing particle interactions.