Why does atom's attraction to electron increase in periods ?

Click For Summary
SUMMARY

The attraction of an atom's outermost electron to the nucleus increases across a period due to the addition of protons, which enhances the positive charge without a corresponding increase in the repulsive forces among electrons. This phenomenon is not accurately described by the notion of "sharing" the positive charge among electrons, as stated in the Edexcel AS Chemistry textbook by Bob Fullick and Ann McDuel. Instead, the electrostatic force experienced by an electron remains strong despite the addition of more electrons, leading to a tighter binding of electrons in positive ions compared to their neutral counterparts.

PREREQUISITES
  • Understanding of atomic structure and electron configuration
  • Familiarity with electrostatic forces and their effects on atomic behavior
  • Knowledge of ionization potential and electron affinity concepts
  • Basic principles of periodic trends in chemistry
NEXT STEPS
  • Research the concept of electrostatic forces in atomic structure
  • Study periodic trends, focusing on atomic radius and ionization energy
  • Examine the differences between neutral atoms and positive ions
  • Review the Edexcel AS Chemistry textbook for accurate descriptions of atomic behavior
USEFUL FOR

Chemistry students, educators, and anyone interested in understanding atomic structure and periodic trends in the behavior of elements.

KingCrimson
Messages
43
Reaction score
1
Why does the nucleus' attraction to the outermost electron increase across a period?
I have been told that this is because each time you go across a period one step to the right, you add one proton and so there is more positive charge, but isn't it true that you also add one electron ? and so the positive charge even though it has increased is divided between more electrons and so the attraction of electrons by the nucleus stays the same ?
This could only mean that the positive charge's attraction to each electron is not divided, but this defies what my a level book says.
thanks in advance
 
Last edited:
Physics news on Phys.org
You're correct, it is not divided.

The electrostatic force a single charge like an electron "feels" from the nucleus increases with the number of protons, and it doesn't decrease as you add more electrons in the same way as the force of Earth's gravity on a single person doesn't decrease as you add more people.

KingCrimson said:
but this defies what my a level book says.
There's probably some misunderstanding there. Can you quote what your book says?
 
Page 75 Edexcel AS chemistry bob fullick and ann mcduel
"A positive ion always has a smaller ionic radius than the original atom, This is because the loss of electron/s means that the remaining electrons each have a greater (share) of the positive charge of the nucleus so are more tightly bound"
they say Share as if the force is divided between electrons.
 
This looks like a blunder to me, but you better wait for other members to voice their opinions.
 
Are you discussing atoms, ions, ionization potential, or electron affinity?
 
KingCrimson said:
Page 75 Edexcel AS chemistry bob fullick and ann mcduel
"A positive ion always has a smaller ionic radius than the original atom, This is because the loss of electron/s means that the remaining electrons each have a greater (share) of the positive charge of the nucleus so are more tightly bound"
they say Share as if the force is divided between electrons.

That's a completely awful wrong terrible somewhat misleading explanation, but it is true that (all else being the same) a positive ion has a smaller diameter than the corresponding neutral atom. The force between the electrons is repulsive, so tends to force the electrons away from one another and outwards. When we remove one electron this force becomes smaller while the attraction to the nucleus remains the same, so the remaining electrons can settle in a bit closer.
 
Nugatory said:
That's a completely awful wrong terrible somewhat misleading explanation, but it is true that (all else being the same) a positive ion has a smaller diameter than the corresponding neutral atom. The force between the electrons is repulsive, so tends to force the electrons away from one another and outwards. When we remove one electron this force becomes smaller while the attraction to the nucleus remains the same, so the remaining electrons can settle in a bit closer.
That's a much better way of putting it. It's due to the net charge (i.e. a difference) and not the "sharing" which is a ratio effect.
 

Similar threads

  • · Replies 2 ·
Replies
2
Views
1K
  • · Replies 36 ·
2
Replies
36
Views
6K
  • · Replies 10 ·
Replies
10
Views
4K
  • · Replies 11 ·
Replies
11
Views
2K
  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 3 ·
Replies
3
Views
1K
  • · Replies 2 ·
Replies
2
Views
1K
  • · Replies 2 ·
Replies
2
Views
1K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 3 ·
Replies
3
Views
2K