JohnZ622 said:
The wire resistance and battery internal resistances are negligible, won't that mean a very large current will follow from one battery to the other creating a dangerous situation?
Depends on the state of discharge.
Think about what's happening around the battery plates
Current has to flow through the electrolyte by ion migration
In a battery that's really badly run down the electrolyte is depleted of ions and the plates are coated with sulfate, both of which increase its resistance.
As you see, at 1 volt per cell electrolyte molality is quite low. Few ions left to conduct.
That's why your charger when connected to an absolutely dead battery initially shows low current .
A battery that's not so badly run down will accept more current.
That's where you can get into trouble with sparks and hydrogen.
I had a battery explode in my face once - an internal intercell connector was cracked raising internal resistance. Thinking it was just badly run down I charged it overnight . That made hydrogen... When daughter hit the starter, "Ka-Pow" the whole top of the battery flew by my head , acid spattering my shirt pants and face. Ruined a good pair of dockers and a dress shirt. Good thing i was wearing glasses...
With the top gone i could see the cheap internal construction of that battery. High current to the starter had melted the last sliver of that cracked intercell connector and ignited the hydrogen.
Lesson - don't scrimp on a car battery. .
Here's an interesting link...
http://ecee.colorado.edu/ecen4517/materials/Battery.pdf
volts vs molality plot came from there
old jim