Why does platinum adsorb hydrogen

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    Hydrogen Platinum
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Discussion Overview

The discussion centers around the phenomenon of hydrogen adsorption on platinum, exploring the underlying reasons for this behavior despite platinum's classification as an inert element. Participants inquire about the principles governing adsorption, the variability among different elements, and the predictability of adsorption properties.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions why platinum, despite being inert, adsorbs hydrogen and asks if there are laws governing the relationship between adsorbents and adsorbate gases.
  • Another participant suggests that the adsorption is a bulk material property, comparing it to how a sponge absorbs water, while noting that the exact mechanisms are not fully understood.
  • A different viewpoint posits that the small size of hydrogen allows it to infiltrate the metal lattice of platinum, contributing to its adsorption.
  • One participant highlights that hydrogen has a particular affinity for platinum-group metals, prompting further inquiry into the reasons behind this preference.
  • There is mention of the relevance of platinum in contexts such as PEM fuel cells and cold fusion, indicating that the specifics of hydrogen adsorption may vary depending on the application.

Areas of Agreement / Disagreement

Participants express varying hypotheses regarding the adsorption of hydrogen on platinum, with no consensus reached on the definitive reasons or principles involved. The discussion remains open-ended with multiple competing views.

Contextual Notes

The discussion does not resolve the underlying assumptions about the nature of adsorption or the specific conditions under which platinum interacts with hydrogen. The complexity of the topic and the dependence on context are acknowledged.

ajayguhan
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Why does platinum adsorbs hydrogen, when platinum being one of the inert element? Is there any law which states about the adsorbent and the adsorbent gas? Why do some elements like platinum absorbs while some elements doesn't adsorb gases!? Is there a way to predict that this element or compound will absorb this kind of substances upto this extent.
 
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It's a bulk material property similar to why some things dissolve in some substance and others don't.
But more like how a sponge soaks up water ...

There are lots of ideas about how Platinum-like metals do what they do, eg.
http://www.chemistryexplained.com/elements/L-P/Platinum.html
... but, basically, nobody much knows for sure last I looked.
 
I thought it was because hydrogen is very very small and likes to get in between everything, including atoms in the metal lattice.
 
Well yeah - but hydrogen is particularly fond of doing that sort of thing with platinum-group metals.
The question is "how come?"

... actually, it says "why?" but I don't like "why" questions.

Note:
OP also has a question about hydrogen cells (specifically electrodes and gas-pressure stuff).
Platinum catalysis is something of a bugbear in PEM fuel cells but also in Pons/Fleischman type "cold-fusion" so I'm waiting for the other shoe to drop.

As usual, the specifics of the answer will depend on the context.
 
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