Why does the heat capacity of solids drop exponentially at low temperatures?

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SUMMARY

The heat capacity of solids drops exponentially at low temperatures due to the freezing of degrees of freedom, as explained by the Debye model. This phenomenon occurs because, at low temperatures, the vibrational modes of the solid's lattice structure become less active, leading to a significant reduction in heat capacity. The discussion emphasizes the importance of understanding the statistical mechanics behind this behavior, particularly the role of the Debye model in describing heat capacity at low temperatures.

PREREQUISITES
  • Understanding of the Debye model for heat capacity
  • Basic knowledge of statistical mechanics
  • Familiarity with the concept of degrees of freedom in solids
  • Awareness of heat capacity and its significance in thermodynamics
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  • Research the mathematical derivation of the Debye model for heat capacity
  • Explore the relationship between temperature and vibrational modes in solids
  • Learn about the limitations of the Debye model at high temperatures
  • Investigate experimental methods for measuring heat capacity in solids
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Students and researchers in physics, materials science, and engineering who are studying thermodynamic properties of solids and the behavior of heat capacity at varying temperatures.

pangru
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According to Einstein (or Debay) model of solids, heat capacity drops exponentially at low temperatures:

300px-Escv.png


question is >> why it changes so dramatically at low temperature
that is physical explanation of this?
 
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Hi,
Don't understand your question -- in the sense that where you found the picture, there also is a derivation of the expression. With a link to Debye for lowest T
Or do you seek an answer like "degrees of freedom are frozen" at low T ?
 
BvU said:
Or do you seek an answer like "degrees of freedom are frozen" at low T ?
yes, something like that :smile:

at low T, heat capacity is very low >> how this could be explained?
without math :biggrin:
 
pangru said:
yes, something like that :smile:

at low T, heat capacity is very low >> how this could be explained?
without math :biggrin:

BvU just did!

Zz.
 
ZapperZ said:
BvU just did!

Zz.
do you mean this? >> degrees of freedom are frozen" at low T
OK. .. and that does frozen degrees of freedom means? :D

Imagine you are Einstein, How would explain this to your grandmother? :D
 
pangru said:
do you mean this? >> degrees of freedom are frozen" at low T
OK. .. and that does frozen degrees of freedom means? :D

Imagine you are Einstein, How would explain this to your grandmother? :D

1. If my grandmother asks me that question, then she would have had some basic knowledge to know the figure she showed me in Post #1. In other words, she would have had to know what "heat capacity" is, what "Debye model" is to describe such heat capacity, the statistical derivation of it, and to know what that figure is saying. This means that she is well-equipped to comprehend the answer.

2. My grandmother was also not a lazy woman. She would have used everything at her disposal to figure out what freezing of the degree of freedom have anything to do with the specific heat curve. She was also pretty sharp to know when an answer to her question was already given and not have missed it this badly.

3. https://www.physicsforums.com/threads/if-you-cant-explain-it-to-your-grandmother.765734/

Zz.
 
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