In the addition of water to an alkene, the carbon atom becomes electron deficient, leading to the formation of a carbocation. When water donates a lone pair to the carbon, the oxygen atom becomes electron deficient as it loses one of its lone pairs, resulting in a positive formal charge on the oxygen. Understanding formal charge calculations is crucial for accurately tracking electron distribution in organic chemistry. While memorization of patterns can be helpful, grasping the underlying principles is emphasized for deeper comprehension. This discussion highlights the importance of formal charge in understanding molecular interactions during reactions.