BC is identified as a two-force member because it only experiences horizontal reactions at B, while AE is not classified as such due to its involvement in shear and bending, necessitating reactions. The discussion highlights that for a two-force member, forces must be collinear along the axis of the link, and since ADE supports additional loads, it cannot be a two-force member. The members are pinned at D, which transmits forces but not moments, affecting how loads are distributed. The absence of applied loads at C means that BDC cannot experience bending or shear, reinforcing its classification as a two-force member. The conversation emphasizes the importance of understanding force reactions and moments in structural analysis.