It would be quite unusual to say that work is delta E mech, unless they are not counting work done by the forces associated with potential energy functions (called "conservative forces") as work! But it normally would be called work, even the conservative forces. If you don't count the work done by conservative forces in the work-energy theorem, then the work done equals the change in mechanical energy (if there's no heat loss). I can't recommend that conceptual approach however, work is too valuable a concept to waste on purely nonconservative forces. Just count all forces as able to do work, and then if there is no heat loss, work is always equal to the change in kinetic energy, you can derive that from F=mA.
So in summary:
work by a single conservative force = - delta U
is only for work done by conservative forces (forces with a potential energy associated with them). This isn't a statement about reality, it is just the definition of potential energy-- it's bean counting.
net work = delta KE
is the work-energy theorem, equivalent to F=mA. This is a statement about how reality works, given the more general definition that net work is the sum of all the work by all the forces (including friction).
work = delta mechanical energy
is only true if you don't count work done by conservative forces as work on the left-hand-side (their - delta U is pulled to the other side of the equation, and absorbed into mechanical energy, just a different way to count those beans). So the meaning of "work" here is external forces applied manually (like a person pulls on a rope or something), or frictional forces. If you include work done by frictional forces, you are not including heat that is dissipated in the mechanical energy, that's just KE+U.
One final note-- when you do inelastic collisions, like objects that stick together, it is generally hard to include the work done there, so you usually drop the attempt to bean count using work, unless you are told the heat dissipated in the elastic collision. Usually you just don't use conservation of energy at all for inelastic collisions, but you can if there is friction, if you can track how much work the friction does.