Which anion could be used to selectively remove silver ions?

In summary, the conversation discusses the use of different anions to selectively remove silver ions from solution. The options are Cl, SO4, or CO3, all of which form precipitates. The group considers which anion would be the most effective and discusses the importance of not precipitating other cations. They also mention considering the molar concentration of Ag+ in the solution and using solubility rules to guide their decision, noting that transition metals are generally insoluble unless paired with a soluble anion.
  • #1
HHH
34
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The question is, which anion could be used to selectively remove silver ions from solution? The options are Cl, SO4, or CO3.

All 3 of them form precipitates, but is there any that is better than the others?
 
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  • #2
Do you know what other cations are present in the solution? If you're trying to selectively precipitate silver ions, it is important that the salt you add does not also precipitate other ions.
 
  • #3
Another thing to consider: for which of the three potential precipitates molar concentration of Ag+ in the saturated solution is the lowest?
 
  • #4
Check your solubility rules and that should guide you. Transition metals are generally insoluble unless paired with another anion which is soluble.
 
  • #5
brake4country said:
Transition metals are generally insoluble unless paired with another anion which is soluble.

And what are "soluble" anions?
 

1. What is an anion?

An anion is a negatively charged ion, meaning it has gained one or more electrons. It is typically written with a minus sign (-) after the chemical symbol.

2. Why is it important to selectively remove silver ions?

Silver ions can be toxic to the environment and can also cause adverse health effects in humans. Therefore, it is important to selectively remove them in order to prevent contamination and potential harm.

3. How do anions selectively remove silver ions?

Anions can selectively remove silver ions through a process called ion exchange. This involves exchanging anions in a solution with the target silver ions, resulting in their removal from the solution.

4. Which anion is commonly used to selectively remove silver ions?

Sulfide (S2-) is commonly used to selectively remove silver ions. This is because sulfide ions have a high affinity for silver ions and can easily form insoluble silver sulfide, which can be removed from the solution.

5. Are there any other anions that can be used to selectively remove silver ions?

Yes, other anions that can be used include cyanide (CN-), thiosulfate (S2O3 2-), and thiourea (CS(NH2)2). These anions also have a high affinity for silver ions and can form insoluble compounds for removal.

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