The complete density matrix would have no repeated indices, or would include a sum over both ##V## indices as well as ##V^*## indices:
$$
\hat\rho_0 = \rho_{a,i,j; b,k,\ell} |a,i,j\rangle\langle b, k, \ell| \equiv \sum_{a,i,j,b,k,\ell} \rho_{a,i,j; b,k,\ell} |a, i, j\rangle\langle b, k, \ell|
$$...