Why doesn't the electron fall into the nucleus?

  • #51


feynmann said:
No one is saying in one sentence disprove QM and in another one praise feynman and yukawa. What was disproved is "Copenhagen Interpretation", not Quantum mechanics.
The probability of wavefunction is "Copenhagen Interpretation", Not "Quantum Mechanics" itself. There is No probability of wavefunction in Bohm's version of Quantum Mechanics

It's clear your knowledge of quantum mechanics is full of nonsense, since you don't even know the difference between quantum mechanics and "Copenhagen Interpretation", what a "Science Advisor". Would you stop calling yourself "Science Advisor"? I certainly don't need your "advice".

I perfectly know the difference, it is custom to drop to the "copenhagen interpretation", since that is the standard in physics today. As we had in another thread "only amateur worries about different interpretations". So QM and Copenhagen interpretation of QM are interchangeable to many (almost all) physicists.

So let us go back to the atom again, it has no definite size, this is an experimental fact as well. If you claim that the atom has a definite size, you should have it backed up with articles. Claim was "hydrogen atoms has definite size. It's size is about the Bohr's radius", now prove it. Also you used the word "superposition" for continuous variable, position, I don't believe that makes sense in Real Analysis...

So let us go back to Yukawa again. You said that Yukawa used the Heisenberg uncertainty relation to show that the strong force is mediated by pions. That is an insult to Yukawa, we actually went through Yukawa's theory in my quantum field class recently, and there is no Heisenberg principle used what so ever, just pure and nice Quantum Field Theory. Many popular science book uses Heisenberg to explain alot, even yukawa's theory, so one will, as you just proved, get the impression that it is used. But now you encountered an Science Advisor, who knows the things we are discussion in detail, since he has worked with these things, not just read them on wikipedia.

One also uses the Heisenberg principle in discussion about Feynman diagrams and virtual particles, but these "explanations" are never used in REAL textbooks. In REAL textbooks, one presents the REAL arguments. The reason for why Heisenberg principle is so applicable to explanations of quantum phenomenon is that is really easy to do so, it is really "the ultimate probabilistic" entity. It is almost like the good ol "God of the gasps", whenever one couldn't find an explanation due to lack of knowledge, one "blaimed" God. Today, people who does not know quantum mechanics uses Heisenberg Uncertainty principle for their explanations...
 
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  • #52


I only use the analogy to explain the effects of inertia on the electron. Only a loss of energy ( in the form of heat ) can bring the electron closer to the nucleus. There is obviously no friction in subatomic space, so there is no other reason that the electron would lose energy.
 
  • #53


Modman said:
I only use the analogy to explain the effects of inertia on the electron. Only a loss of energy ( in the form of heat ) can bring the electron closer to the nucleus. There is obviously no friction in subatomic space, so there is no other reason that the electron would lose energy.

Well in your analogy there IS reason the electron would lose energy if it were "orbiting" around the nucleus. It can be shown that an accelerating electron radiates energy. If it's in "orbit" in the usual sense, there is some sort of centripetal acceleration at all times. The stability of the energy state has nothing to do with it being frictionless system.
 
  • #54


Another way to think of this is what happens once the electon is within the bohr radius (53 picometers) of the hydrogen proton? The max energy that holds the electron to the proton is 13.6evolts, that does not increase, ie you never need more then 13.6 evolts of energy to pull an electron away from a hydrogen proton.

If one views the bohr radius as about the size of the first s orbital of hydrogen, it appears that it does not matter where the electon is, it does not require more energy to pull it out even if it is very very close to the proton.

Does this not lead to the conclussion that the hydrogen electron does not feel the pull of the proton (ie, does not gain energy beyond 13.6 evolts) once inside the first s orbital?
 
  • #55


thoughtgaze said:
Well in your analogy there IS reason the electron would lose energy if it were "orbiting" around the nucleus. It can be shown that an accelerating electron radiates energy. If it's in "orbit" in the usual sense, there is some sort of centripetal acceleration at all times. The stability of the energy state has nothing to do with it being frictionless system.

the only possible explanation is that the electron is spread out over the whole atom due to the uncertainty principle and it is the whole 'electron cloud' that is spinning around the nucleus. hence the electric and magnetic fields arent changing so there is no radiation of energy.

ytuab said:
Quantum physics replaced Bohr-Sommerfeld theory in 1920's.
Since then many phsicists such as Pauli, Heisenberg, Dirac... have given up explaining the
motion of an electron concretely.

because by equating the angular momentum of the spinning sphere of the electron to 1/2
h-bar, the sphere speed leads to about one hundred times the speed of light.

the whole electron cloud would not be spinning faster than the speed of light.
ytuab said:
The orbital angular momentum of the electron in the ground state of the hydrogen atom is zero, so the Coulomb potential is infinitely negative when the electron is close to the nucleus.

but the electron still has spin
 
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  • #56


edguy99 said:
Another way to think of this is what happens once the electon is within the bohr radius (53 picometers) of the hydrogen proton? The max energy that holds the electron to the proton is 13.6evolts, that does not increase, ie you never need more then 13.6 evolts of energy to pull an electron away from a hydrogen proton.

If one views the bohr radius as about the size of the first s orbital of hydrogen, it appears that it does not matter where the electon is, it does not require more energy to pull it out even if it is very very close to the proton.

Does this not lead to the conclussion that the hydrogen electron does not feel the pull of the proton (ie, does not gain energy beyond 13.6 evolts) once inside the first s orbital?

If the first orbital is a sort of stable state then the electron can feel an even greater force if it got even closer to the nucleus for example if a collision pushed it momentarily inwards before it moved outwards..This would not necessarily change the excitation or ionisation energies because energy lost on the inward journey between levels might be regained on the outward journey.It's just a thought and I will give it some more thought.
 
  • #57


ytuab said:
The orbital angular momentum of the electron in the ground state of the hydrogen atom is zero, so the Coulomb potential is infinitely negative when the electron is close to the nucleus.

The Coulomb potential is infinitely negative as long as the nucleus is modeled as a point charge. Angular momentum has nothing to do with it at all.

The divergence of the Coulomb term is canceled out by the divergence of the kinetic-energy term. The wave function is not divergent at the nucleus, just non-smooth. It forms a cusp.
 
  • #58


edguy99 said:
Another way to think of this is what happens once the electon is within the bohr radius (53 picometers) of the hydrogen proton?

A hydrogen electron in the 1s state spends almost 1/3 of its time within the Bohr radius. So?

The max energy that holds the electron to the proton is 13.6evolts, that does not increase, ie you never need more then 13.6 evolts of energy to pull an electron away from a hydrogen proton.

That'd be conservation of energy.

If one views the bohr radius as about the size of the first s orbital of hydrogen, it appears that it does not matter where the electon is, it does not require more energy to pull it out even if it is very very close to the proton.

That doesn't make sense. Why do you need to assume the Bohr radius is the 'size' to then conclude that it does not matter where the electron is?

An orbital is an energetic eigenstate of the Schrödinger equation, and with the exception of the occasional infinitesimally-small node, they have nonzero values for the location-probability over all space. So knowing the location of an electron at any given moment tells us nothing about its energy. Which wouldn't necessarily be the case if it could be described classically.

Does this not lead to the conclussion that the hydrogen electron does not feel the pull of the proton (ie, does not gain energy beyond 13.6 evolts) once inside the first s orbital?

Again, that's just conservation of energy. That's never been an issue. The issue is why this energy couldn't be radiated away.
 
  • #59


alxm said:
Again, that's just conservation of energy. That's never been an issue. The issue is why this energy couldn't be radiated away.

If an electron inside of the bohr radius (53pm) no longer feels an attraction to the proton, then presumbably there is no need to radiate energy. Doesn't it basically just sit around somewhere inside "about" this radius "most" of the time?
 
  • #60


granpa said:
the only possible explanation is that the electron is spread out over the whole atom due to the uncertainty principle and it is the whole 'electron cloud' that is spinning around the nucleus. hence the electric and magnetic fields arent changing so there is no radiation of energy.

the whole electron cloud would not be spinning faster than the speed of light.
but the electron still has spin

If the whole electron cloud is spinning, this means the orbital angular momentum in the ground state of hydrogen is not zero. And it also radiates energy outside.

alxm said:
The Coulomb potential is infinitely negative as long as the nucleus is modeled as a point charge. Angular momentum has nothing to do with it at all.

The divergence of the Coulomb term is canceled out by the divergence of the kinetic-energy term. The wave function is not divergent at the nucleus, just non-smooth. It forms a cusp.

If the nucleus is not a point charge, the electron penetrates into the nucleus many times a day. The electron is probably scattered by the nucleus.
Experimentally the scattering of electrons from nuclei has given us the most precise information about nuclear size and charge distribution.
 
  • #61


edguy99 said:
If an electron inside of the bohr radius (53pm) no longer feels an attraction to the proton, then presumbably there is no need to radiate energy. Doesn't it basically just sit around somewhere inside "about" this radius "most" of the time?

Now that's just crazy talk.
 
  • #62


what radiates energy outside?
 
  • #63


alxm said:
Wrong. |\psi(\mathbf{x},t)|^2 is a particle's spatial probability density in quantum mechanics. Regardless of the interpretation. .

Wrong! It's deterministic in Bohm's version of QM. That's why Einstein says that "God does Not play dice with the universe". Bohm believed in "Copenhagen Interpretation", but after talking to Einstein, He changed his mind to "Hidden Variable" interpretation

--Note: pay attention to item #2;

<Principles of Copenhagen Interpretation> http://en.wikipedia.org/wiki/Copenhagen_interpretation

1. A system is completely described by a wave function ψ, which represents an observer's knowledge of the system. (Heisenberg)
2. The description of nature is essentially probabilistic. The probability of an event is related to the square of the amplitude of the wave function related to it. (Born rule, due to Max Born)
3. Heisenberg's uncertainty principle states the observed fact that it is not possible to know the values of all of the properties of the system at the same time; those properties that are not known with precision must be described by probabilities.
4. Complementarity principle: matter exhibits a wave-particle duality. An experiment can show the particle-like properties of matter, or wave-like properties, but not both at the same time.(Niels Bohr)
5. Measuring devices are essentially classical devices, and measure classical properties such as position and momentum.
6. The correspondence principle of Bohr and Heisenberg: the quantum mechanical description of large systems should closely approximate the classical description.
 
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  • #64


feynmann said:
Wrong! It's deterministic in Bohm's version of QM. That's why Einstein says that "God does Not play dice with the universe". Bohm believed in "Copenhagen Interpretation", but after talking to Einstein, He changed his mind to "Hidden Variable" interpretation

--Note: pay attention to item #2;

<Principles of Copenhagen Interpretation> http://en.wikipedia.org/wiki/Copenhagen_interpretation

1. A system is completely described by a wave function ψ, which represents an observer's knowledge of the system. (Heisenberg)
2. The description of nature is essentially probabilistic. The probability of an event is related to the square of the amplitude of the wave function related to it. (Born rule, due to Max Born)
3. Heisenberg's uncertainty principle states the observed fact that it is not possible to know the values of all of the properties of the system at the same time; those properties that are not known with precision must be described by probabilities.
4. Complementarity principle: matter exhibits a wave-particle duality. An experiment can show the particle-like properties of matter, or wave-like properties, but not both at the same time.(Niels Bohr)
5. Measuring devices are essentially classical devices, and measure classical properties such as position and momentum.
6. The correspondence principle of Bohr and Heisenberg: the quantum mechanical description of large systems should closely approximate the classical description.

Let me then post what is said about Bohm interpretation on Wiki:

http://en.wikipedia.org/wiki/Bohm_interpretation

* The particles form a statistical ensemble, with probability density \rho(\mathbf{x},t) = |\psi(\mathbf{x},t)|^2

Although we don't know the position of any individual particle before we measure them, we find after the measurement that the statistics conform to the probability density function that is based on the wavefunction in the usual way.


You have still not said "thank you" to me for telling you the truth about atom sizes and Yukawa theory :-D
 
  • #65


feynmann said:
Wrong! It's deterministic in Bohm's version of QM.

You continue to confuse something being described statistically, i.e. as a probability with something being indeterministic. They're not the same thing, and assuming it is is simply wrong.

In fact, it's not only wrong, it's a completely bizarre mistake to make. Because the probabilities as viewed in the Copenhagen interpretation are the only example of truly non-deterministic probabilities anywhere. The probability of rolling a 7 on a pair of dice is 1/6. That doesn't mean that dice move indeterministically.

And again, |psi|^2 is a probability, regardless of your interpretation. Go read about the Bohm interpretation. The fact that |psi|^2 is a probability is fundamental postulate of quantum mechanics, from which the entire theory is derived. The normalization condition, for instance, follows immediately and trivially from it.

I'll have to concur with malawi_glenn here, I think you need to read an textbook on Quantum Mechanics. Popular-scientific accounts are not a substitute. Einstein quotes aren't a physical argument.
 
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  • #66


Can somebody clarify something please?I just Wikigoogled to get a feeling of what Mr Bohm is all about and was informed that his interpretation gives the same theoretical predictions as other interpretations such as Copenhagen.Is that the case because the article had sort of disclaimers at the top including expressing the need for an expert on the subject.For a brief moment I thought I was that expert but then I came back to reality.:biggrin:
 
  • #67


Dadface said:
Can somebody clarify something please?I just Wikigoogled to get a feeling of what Mr Bohm is all about and was informed that his interpretation gives the same theoretical predictions as other interpretations such as Copenhagen.Is that the case because the article had sort of disclaimers at the top including expressing the need for an expert on the subject.For a brief moment I thought I was that expert but then I came back to reality.:biggrin:

we have zillions of old threads about Bohm Interpretation here.
 
  • #68


alxm said:
I'll have to concur with malawi_glenn here, I think you need to read an textbook on Quantum Mechanics. Popular-scientific accounts are not a substitute. Einstein quotes aren't a physical argument.

Same holds with R. Feynman quotes, as someone said "In physics, we don't have any prophets".
 
  • #69


Dadface said:
Can somebody clarify something please?I just Wikigoogled to get a feeling of what Mr Bohm is all about and was informed that his interpretation gives the same theoretical predictions as other interpretations such as Copenhagen.Is that the case because the article had sort of disclaimers at the top including expressing the need for an expert on the subject.For a brief moment I thought I was that expert but then I came back to reality.:biggrin:

I attended a course on this at Cambridge which I found very useful. The lectures are online http://www.tcm.phy.cam.ac.uk/~mdt26/pilot_waves.html" .
 
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  • #70


Dadface, all interpretations give the same predictions because they're not really scientific theories (in the logical-positivist or Popperian sense). They amount to different explanations of what the wave function is.

The wave function is such that it results in a probability distribution of possible states. This is a fundamental postulate from which quantum mechanics is derived, not an interpretation thing. The interpretations amount to why this is the case.

The most obvious assumption (to me at least) would be that there are 'hidden variables'. We're getting a probability, not because the thing is truly random, but because there's a lack of data. A system has some state prior to it being measured, we just don't know what it is. I feel that's the 'obvious' conclusion, because that's the normal state of affairs when something is described probabilistically. As I said, there's a 1/6 chance of rolling a 7 on a pair of dice - but if you knew everything about that dice roll beforehand - then you should be able to predict exactly what the result should be.

The Copenhagen interpretation claims, on the other hand that there are no hidden variables. In other words, the state really is 'undefined' before it's measured. That's what quantum 'weirdness' is largely about, precisely because that's not how probabilities usually work. "Schrödingers Cat" was all about highlighting the weirdness of this interpretation, by taking it to the macroscopic level.

At the moment, nobody has been able to come up with any real experiment to prove (or disprove) hidden variables (much less determine what they are). Many have tried. So the end result is that no interpretation is experimentally testable - or practically significant. There's no practical difference between having a system that's non-deterministic, and one that's deterministic but in terms of things that cannot be measured.

Still, 'hidden variables' is an appealing idea. The problem is with Bell's theorem, which didn't prove or disprove hidden variables, but experimentally (the famous Aspect experiment, etc) showed that if they exist, that they cannot be local. Which is also very weird. (in other words, a kind of faster-than-light interaction is going on).

Personally, I'm mostly an adherent of malawi_glenn's quote: "Only amateurs concern themselves with interpretations". It makes no difference what interpretation you use. I don't even see why you'd bother thinking about it - unless it can be experimentally disproven, it's metaphysics or theology to me, and no more interesting than debating how many angels can dance on the head of a pin.

I'm not entirely certain interpretations are needed. They all hinge on the idea of probabilities that arise from measurement. But that implies a separation into 'measuring' and 'measured' systems which isn't really possible (imho). The wave function of the universe as a whole never gets 'measured' and would have a perfectly deterministic time evolution.
 
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  • #71


Thank you malawi glen.I should have searched first. I can be so dopey at times.

Thank you camboy.That looks brilliant.I just want a taster of what its all about and I think I have got that already just by looking at the opening bits.When I get time I will look at the rest.

And thank you alxm.I saw your message at the moment I posted this .I have to go now and I look forward to reading it later.
 
  • #72


malawi_glenn said:
Same holds with R. Feynman quotes, as someone said "In physics, we don't have any prophets".

Suppose you lived in Amazon and you have never heard about Einstein's relativity or Schrodinger Equation. *** Can you figure it out by yourself? I doubt. That why they got Nobel prize but we don't
 
  • #73


feynmann said:
Suppose you lived in Amazon and you have never heard about Einstein's relativity or Schrodinger Equation. *** Can you figure it out by yourself? I doubt. That why they got Nobel prize but we don't

And the reason for they got Nobel prize was that other physicists can verify their results independently etc. Just because a guy who has got the Nobel Prize does not per automatic make him pass all peer reviews, everything has to be tested.

The person I quoted was Weinberg, if you know who that is ...

and your "analogy" is not even applicable, it is not the amazon tribe guys who give away Nobel Prizes.. LOL
 
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  • #74
alxm said:
At the moment, nobody has been able to come up with any real experiment to prove (or disprove) hidden variables (much less determine what they are). Many have tried. So the end result is that no interpretation is experimentally testable - or practically significant. There's no practical difference between having a system that's non-deterministic, and one that's deterministic but in terms of things that cannot be measured.

Still, 'hidden variables' is an appealing idea. The problem is with Bell's theorem, which didn't prove or disprove hidden variables, but experimentally (the famous Aspect experiment, etc) showed that if they exist, that they cannot be local. Which is also very weird. (in other words, a kind of faster-than-light interaction is going on).

I wouldn't agree with this statement. There are a number of very powerful experiments which disprove ALL hidden variable interpretations. Please keep in mind that advocates of some of these interpretations do not accept this evidence, and in some cases those same advocates assert they do not apply (for example Bohmians generally class BM/dbb theory as contextual and therefore these No-Go theorems don't apply). So I will let you form your own opinion. However, these are some of the recent proofs:

Experimental test of quantum contextuality in neutron interferometry: Test of the Kochen-Specker theorem.

http://www.iop.org/EJ/article/1367-2630/11/3/033011/njp9_3_033011.html: Hardy's.

Leggett's theorem without inequalities: Leggett's.

Comprehensive proof of the Greenberger-Horne-Zeilinger Theorem for the four-qubit system: Don't forget the GHZ theorem!

Mermin's 1990 summary on No-Go Theorems

So all of these are completely independent of Bell, and do not require the assumption of locality. Not trying to bait the Bohmians with these, as we know already they don't acknowledge any of it.
 
  • #75


DrChinese said:
I wouldn't agree with this statement. There are a number of very powerful experiments which disprove ALL hidden variable interpretations. Please keep in mind that advocates of some of these interpretations do not accept this evidence, and in some cases those same advocates assert they do not apply (for example Bohmians generally class BM/dbb theory as contextual and therefore these No-Go theorems don't apply).

So, in your opinion, what is the way to go? What are we to do with Schrodinger's cat?
 
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  • #76
  • #77


granpa said:
I'm not sure you understood me. here is what I was talking about:
https://www.physicsforums.com/showpost.php?p=1287217&postcount=8

(if we could think of the electron in the H atom as a continuous distribution of charge, it shouldn't radiate.)

--- Your above hydrogen atom model is so interesting, and points out an important thing.

But you forget one thing.
If the whole hydrogen atom is stopping still, it does not radiate as you say.
But actually the whole hydrogen atom is oscillating and moving about, So it loses energy by emitting electromagnetic waves in your model.
 
  • #78


the electron doesn't have to be motionless to not radiate. it just has to be smeared out over the whole orbit.

whether the hydrogen atom as a whole is moving or oscillating or not is irrelevant to the topic at hand which is 'why doesn't the electron fall into the nucleus'. I have no idea why you would even bring it up.

a mass of warm hydrogen atoms will indeed radiate heat radiation until it cools and the atoms are no longer moving. so what?
 
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  • #79


granpa said:
the electron doesn't have to be motionless to not radiate. it just has to be smeared out over the whole orbit.

Only electrons just don't act like that.

To begin with, the Thomas-Fermi model, and by extension, any such simple electrostatic model that assumes electrons have constant momentum, cannot form chemical bonds and stable molecules. That's even been rigorously mathematically proven. (The Thomas-Fermi theory of atoms, molecules and solids, EH Lieb, B Simon - Adv. Math, 1977)

There is no classical or semi-classical model of atoms that comes even close to being useful, even as an approximation.
 
  • #80


I don't know anything about the Thomas-Fermi model and I very much doubt its anything like what I'm describing.

what on Earth do you mean by 'constant momentum'? do you mean constant angular momentum?

and yes I am sure that chemical bonds (electron pairing) require a quantum mechanical explanation. so what? my point was simply to show how the electron can keep from falling into the nucleus

and now that I think about it, what do you mean 'electrons don't act like that'? that's pretty much what quantum mechanics is all about. the electron becomes smeared out over the whole atom due to the uncertainty principle.but these discussions go round and round and nothing is ever resolved. whatever your answers are there is nothing I can add at this point that others can't plainly see for themselves.
 
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  • #81


alxm said:
Personally, I'm mostly an adherent of malawi_glenn's quote: "Only amateurs concern themselves with interpretations". It makes no difference what interpretation you use. I don't even see why you'd bother thinking about it - unless it can be experimentally disproven, it's metaphysics or theology to me, and no more interesting than debating how many angels can dance on the head of a pin.

It was originally me. And I agree - until you can measure it, arguing about something can be many things, but science is not one of them.

I'd go further and say that fundamental question interpretations are asking is "what is happening when we aren't measuring anything"? Of course, by construction, this is unanswerable.

DrChinese said:
I wouldn't agree with this statement. There are a number of very powerful experiments which disprove ALL hidden variable interpretations.

I agree with this.
 
  • #82


granpa said:
I don't know anything about the Thomas-Fermi model and I very much doubt its anything like what I'm describing.

what on Earth do you mean by 'constant momentum'? do you mean constant angular momentum?

Sounds like a hasty conclusion if you don't know anything about it. And yes, it means both momentum and angular momentum. Such as would be the case with an electronic 'cloud' at a fixed distance, which seemed to be what you envisioning.


and yes I am sure that chemical bonds (electron pairing) require a quantum mechanical explanation. so what? my point was simply to show how the electron can keep from falling into the nucleus

But if you use an un-physical model to do so, it doesn't actually show anything.

and now that I think about it, what do you mean 'electrons don't act like that'? that's pretty much what quantum mechanics is all about. the electron becomes smeared out over the whole atom due to the uncertainty principle.

And that's part of the point I was making. If you think a quantum mechanical description of an bound electron simply means replacing a point charge with a static charge-density 'cloud', then you're simply wrong, because you have to account for the complicated dynamics of motion of the electrons. Even though the charge-density distribution is constant, electrons move, dynamically and have substantial kinetic energy. Any model based soley on electrostatic interactions is going to fail badly.
 
  • #83


alxm said:
And that's part of the point I was making. If you think a quantum mechanical description of an bound electron simply means replacing a point charge with a static charge-density 'cloud', then you're simply wrong, because you have to account for the complicated dynamics of motion of the electrons. Even though the charge-density distribution is constant, electrons move, dynamically and have substantial kinetic energy. Any model based soley on electrostatic interactions is going to fail badly.
This isn't suggesting that electrons "move" continuously, right?
 
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  • #84


I find this very interesting, and the term electron cloud, I really like.

Because I only have a limited understanding of all this, I try to build a picture in my mind of something large enough to interact with, in this case I see the atom the size of a golf ball. At this size if we take an atom (say copper) with a single electron in the outer shell, the speed of the outer electron circling the nucleus, by rough math, is over 120 billion revolutions per second. At this size the electron and nucleus will still be too small to see, in fact the outer shell would be invisible, but feel like a solid object.

The question I have is, has anyone ever purposed a therory of air or a gas like substance being bound inside the valence shell, and equally divided between the other shells, I see this like compressed air inside a basketball. Heat would have an effect and an expansion and contraction would take place.
At the speed an electron moves, it seems a seal barrier might exist, and all shells would react to any energy change.

Just a thought that popped into my brain as I was reading through the thread, I did look at some other threads that had been linked by Marlon (I think). One of those threads mentioned "Kato's Theorem" but I have not found anything yet.

Don't worry, I'm sure this will be my only post here.:wink:

Ron
 
  • #85


Vanadium 50 said:
It was originally me. And I agree - until you can measure it, arguing about something can be many things, but science is not one of them.

That is one of my favourite quotes of all times :!)
 
  • #86


RonL said:
The question I have is, has anyone ever purposed a therory of air or a gas like substance being bound inside the valence shell, and equally divided between the other shells, I see this like compressed air inside a basketball. Heat would have an effect and an expansion and contraction would take place.
At the speed an electron moves, it seems a seal barrier might exist, and all shells would react to any energy change.

Ron
Hi RonL,

The thing you appear to have overlooked is that "air" is made of molecules, which are themselves composed of atoms.

It's counter-intuitive but a bound electron is not stationary. And it's not moving either.
 
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  • #87


DrChinese said:
I wouldn't agree with this statement. There are a number of very powerful experiments which disprove ALL hidden variable interpretations.

You don't mean to say local hidden variable? Even unlocal hidden variable interpretations have been disproven? I was unaware of this.
 
  • #88


WaveJumper said:
Hi RonL,

The thing you appear to have overlooked is that "air" is made of molecules, which are themselves composed of atoms.

It's counter-intuitive but a bound electron is not stationary. And it's not moving either.

Thanks for the reply,
The mention of "air or gas like substance" was only to help build a thought.

I'm a long way from knowing enough to throw anything else out, but when I read about density of black holes, my little pea brain thinks something has to fill the voids from the nucleus to the outer shell.:redface:

Guess I better get back to things i can see.:biggrin:
 
  • #89


WaveJumper said:
Hi RonL,

The thing you appear to have overlooked is that "air" is made of molecules, which are themselves composed of atoms.

It's counter-intuitive but a bound electron is not stationary. And it's not moving either.

What about particle in a box? http://en.wikipedia.org/wiki/Particle_in_a_box
<Particle in a box> is a bound state and its potential energy is all zero.
It's absurd to suggest that it's Not moving in the box. What else can it do in the box, just sit there?
 
  • #90


feynmann said:
What about particle in a box? http://en.wikipedia.org/wiki/Particle_in_a_box
<Particle in a box> is a bound state and its potential energy is all zero.
It's absurd to suggest that it's Not moving in the box. What else can it do in the box, just sit there?

You have to define pecisely what you mean by "moving". So, you need to write down some observable, e.g. the momentum operator, and look at the expectation value. In case of a particle in a box in some energy eigenstate, the expectation value of the momentum is zero. The particle in an energy eigenstate is in a superposition of two states with opposite momenta.
 
  • #91


RonL said:
The question I have is, has anyone ever purposed a therory of air or a gas like substance being bound inside the valence shell, and equally divided between the other shells, I see this like compressed air inside a basketball. Heat would have an effect and an expansion and contraction would take place.
Ron

that was my first thought too. but the electron is a single indivisible particle. if it seems odd to you that it can be a single indivisible particle and at the same time be spread out over an entire orbital then it shouldnt. it can even be spread out simultaneously over several orbitals (as when it is absorbing or emitting light). that's called 'superposition'.
 
  • #92


feynmann said:
So, in your opinion, what is the definition of moving?

In quantum mechanics, it makes sense to define a particle to be moving if it is described by some wavepacket. It then has an approximate position and momentum. You can also argue that since a plane wave represents a particle with precisely determined momentum, such a state should also be considered to be "moving". However, in that case, the state is not evolving in time (apart from a phase factor).

Thing is that you can't separately specify momentum and position in quantum mechanics. Once you've specified all the mometum components of a state, the state is completely fixed; all the position components of the state thus fixed.

In classical physics you can consider momentum and position to be completely independent. Our notion of "motion" is grounded in classical physics, so it is not a well defined concept to start with.

It is similar to building a house out of bricks and then looking at the house from some distance so that you don't see the individual bricks anymore. You can make all sorts of objects with different shapes out of bricks. But if you look closely and you see the individual bricks you will be constrained in what shapes you can make. You can only make 90 degree turns, so smooth curves do not exist at this level.

Similarly, we can build a state that looks like a particle moving from one position to another by making a wavepacket. If you look at it from a large length scale and you cannot resolve the width of the wavepacket, you see what looks like a particle that seems to have a definite position which is moving at a definite velocity.

But what we see is an illusion. The laws of physics forbid that such a state could exist at all. Yet, we have defined the very concept of motion to refer to exactly such a state.
 
  • #93


granpa said:
that was my first thought too. but the electron is a single indivisible particle. if it seems odd to you that it can be a single indivisible particle and at the same time be spread out over an entire orbital then it shouldnt. it can even be spread out simultaneously over several orbitals (as when it is absorbing or emitting light). that's called 'superposition'.

My thought stemed from the many times i have looked at something through a spinning prop, and knowing from experience that a dense object will not pass through a shop fan. The electron has small mass and due to it's velocity, is spread all around the shell area as though it were a solid wall. If any substance exist that fills spaces between shells down to the nucleus, it seems that the movements might be somewhat like our upper atmosphere, where layers move past each other yet do not mix.

I feel that a thought is the start of any learning process, for me, I'm sure I'll look back at this in the future and sink a little lower in my chair, or it might be the start of something special:biggrin: for me at least.
 
  • #94


you are talking as though the electron shell were hollow. it isnt.
 
  • #95


granpa said:
you are talking as though the electron shell were hollow. it isnt.

WELL, that sure changes things:eek:
 
  • #96


Count Iblis said:
You have to define pecisely what you mean by "moving". So, you need to write down some observable, e.g. the momentum operator, and look at the expectation value. In case of a particle in a box in some energy eigenstate, the expectation value of the momentum is zero. The particle in an energy eigenstate is in a superposition of two states with opposite momenta.

It should be noted that any stationary state will have an expectation value of zero for the momentum. Eigenstates for the particle in a box, hydrogen atom, etc. derived from the time-independent Shroedinger equation will all have zero expectation value for the momentum.
 
  • #97


Matterwave said:
You don't mean to say local hidden variable? Even unlocal hidden variable interpretations have been disproven? I was unaware of this.

As you say, the generally accepted view is that there can be no successful local hidden variable theories. I generally stick to the solid stuff (such as Bell). However...

I would say we are very close to the point where even non-local HV theories will be generally considered as "no-go". Now, if we want to debate the underlying validity of the science, that belongs in another thread. And I am not advocating this position anyway, as there is currently a lot of controversy in the area. But there is a LOT more that just a few papers on the subject. And there is a LOT more that just a few people who have already come to this conclusion. The conclusion being based on the following approaches: Kochen-Specker, GHZ, Hardy and Leggett. So my answer is based on my opinion of where the scientific winds are blowing. And I think that HV candidates will have a tough time against these.

Now for the Bohmians: I personally am very interested in finding the best answers to these and other questions about non-locality as an approach. Honestly, it is the most "logical" explanation. And I realize that Bohmians do not consider theirs a non-contextual theory (although I do because it claims to be deterministic). We are lucky to have several top-notch Bohmian theorists on this board, and I think their contributions are very exciting. So I certainly hope no one takes offense because I am not trying to stir up a hornet's nest.

But my opinion doesn't really matter anyway, what I am really saying is that the scale is in the process of tipping in the view of the scientific community at large - and I consider this a relatively new development. If this were a boxing match: I would be hoping I had bet against HV approaches. But the match is not yet over, and I expect there will be a lot of relevant interesting papers coming out in the few years. :smile:
 
  • #98


WaveJumper said:
This isn't suggesting that electrons "move" continuously, right?

They're in constant motion, yes. But they don't move continuously as in 'a continuous path', no. But that much has already been established when saying they don't have a definite location.

See, there's a very common pedagogical problem here. First people learn about the Bohr model and how that's wrong - the electrons don't have a definite location, and are instead described by a location-probability distribution (orbital).

It's then easy, and very common, to make the mistake of thinking that that's the whole picture - that the electron isn't moving, but is stationary - because the probability distribution is stationary. But that would only be half the picture. They still move. Just not in continuous paths. There's no accounting for purely dynamical effects such as correlation energy (the effect on kinetic energy from the correlated motions of electrons), unless you actually think of them as moving.

Is it conceptually difficult to reconcile the idea that the thing is moving, yet has a constant distribution of location-probabilities? Yes. But that's just quantum mechanics for you. Neither particle nor wave, you know.
 
  • #99


alxm said:
Is it conceptually difficult to reconcile the idea that the thing is moving, yet has a constant distribution of location-probabilities? Yes. But that's just quantum mechanics for you. Neither particle nor wave, you know.

How is it conceptually difficult? You can take an analogy to be the motion of a particle oscillating on a pendulum. The probability of measuring the particle at some point at some random time will be constant yet the thing is moving. The probability density is greatest at the turning points of oscillation and is minimum at the equilibrium point.
 
  • #100


thoughtgaze said:
How is it conceptually difficult? You can take an analogy to be the motion of a particle oscillating on a pendulum. The probability of measuring the particle at some point at some random time will be constant yet the thing is moving. The probability density is greatest at the turning points of oscillation and is minimum at the equilibrium point.

These two statements that I highlighted appear to be contradictory to each other.

The reason why the scenario is conceptually difficult is that it makes OTHER issues difficult. A pendulum has its bob a specific location as a specific time, not spread out all over its trajectory, the latter of which is the conventional picture adopted by standard QM. And there ARE consequences of such a scenario, ranging from molecular bonds, to the existence of the coherent gap in SQUIDs experiments.

Besides, is the mathematics describing the two systems even equivalent?

Zz.
 

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