Chemicals that freeze at less than 60 Kelvin

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The discussion centers on finding a comprehensive list of chemicals that freeze at temperatures below 50 K. Participants note that while organic molecules are known to freeze at low temperatures, specific examples and a complete reference are hard to come by. A suggestion is made to explore the recently released melting point data from Alfa Aesar, which is part of an open access project. It is mentioned that searching for chemicals with freezing points around 100 K may yield better results, with examples like silanes and certain conjugated organic compounds. Methane is also cited as freezing around 90 K. Additionally, the CRC Handbook of Chemistry is recommended as a potential resource, along with a link to a melting point chart that includes elements but omits deuterium, which freezes at about 19 K. Participants express interest in sharing any findings related to the topic.
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Does anyone know of a reference to a list of all known chemicals that freeze at less than 50 K? I know lots of organic molecules do, but I don't know which ones. I also can find the freezing points of all the elements pretty easy, but chemicals are proving more elusive.
 
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Albertgauss said:
Does anyone know of a reference to a list of all known chemicals that freeze at less than 50 K? I know lots of organic molecules do, but I don't know which ones. I also can find the freezing points of all the elements pretty easy, but chemicals are proving more elusive.

Alfa Aesar just released a rather large amount of chemical melting point data the other year as part of an "open access" project. If you Google that, you should be able to find that information - as well as other related data sets that are part of this project.

My recollection is that you are probably best off not holding your breath. If you were looking for something around 100 K, you'd have better luck - silanes and certain conjugated organic chemicals can freeze around that point. Even methane freezes at around 90 K (as memory serves).

If you find anything interesting, though, please share! I'd sincerely love to see what you dig up.
 
CRC handbook of chemistry could be a good place to look
 
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