Arnold, dextercioby,
Yes, you've convinced me that Maxwell's theory has a set of 10 generators, e.g., those defined as classical analogs of QED functions [tex]H, \mathbf{K}, \mathbf{P}, \mathbf{J}[/tex] of operator fields [tex]A^{\mu}, J^{\mu}[/tex] in subsection 8.1.2. So, formally, it is OK as a relativistic theory.
However, I think, it is important to note that this alleged quantum-classical correspondence is only formal. The point is that quantum QED generators in subsection 8.1.2 do not form a viable physical theory. So, its classical limit cannot be viable too. The bad features of QED in 8.1.2 are seen from the fact that the S-matrix computed with the Hamiltonian (8.10) is divergent. Of course, in QED this problem is fixed by adding counterterms, which effectively result in infinite masses and charges. If we were to take a classical limit of QED with counterterms, we wouldn't get the familiar Maxwell's theory.
However, even QED with counterterms is not satisfactory as a quantum theory of interacting charges and photons. As I discuss in section 10.1, the time evolution of states is not acceptable in this approach. The next step should be taken, which is a unitary transformation of the QED Hamiltonian with counterterms to the dressed particle form. Then, finally, we obtain an acceptable quantum theory with a finite Hamiltonian, realistic time evolution of particle states, and experimentally confirmed S-matrix. But the classical limit of this theory is not going to look as Maxwell's theory at all. It looks more like the Darwin-Breit Hamiltonian.
dextercioby said:
[...] the quantum theory must generalize the classical one and could(and should have novel features compared to it. [...] the classical one is to be postulated [...] to the classical Poisson bracket one must find a proper quantum commutator and not viceversa.
I strongly disagree with the idea that first we must postulate a classical theory and then "quantize" it in order to get a quantum-mechanical counterpart. The most general and exact theory of nature must be both quantum and relativistic. So, if we don't want to make mistakes, we must first postulate a self-consistent fully quantum approach with Hilbert space, commutators, and all that. Then, the classical analog should be obtained in the limit [tex]\hbar \to 0[/tex]. In this limit we may lose some fine quantum features, but, at least, we can be confident that our classical approach has a solid foundation in quantum postulates. If for some reason we find that the classical limit doesn't work or disagrees with experiment, then we should modify our quantum theory and try again.
The idea of "quantization" can possibly work as a heuristic tool for guessing the form of yet unknown quantum theory in the absence of other theoretical options. But I wouldn't consider "quantization" as a rigorous theoretical mechanism.
Eugene.