Distinguish covalent and partially covalent chemical bonds

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Covalent and partially covalent bonds are often misunderstood, with distinctions not always clear-cut. Purely covalent bonds are primarily found in homonuclear diatomic molecules, such as O2 or N2, where atoms share electrons equally. However, even these bonds can exhibit some ionic character due to differences in electronegativity. The classification of bonds as covalent or ionic is not precise; it exists on a continuum with many compounds displaying characteristics of both types. The boundary between covalent and ionic bonds is largely a matter of convention. Advanced methods like Bader analysis can help quantify the contributions of covalent and ionic character in bonds, providing a more nuanced understanding of their nature.
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I read some books which mention about covalent and partially covalent chemical bonds. However, I cannot distinguish between them. Who can help me?
Thank you very much!
 
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The only purely covalent bonds I can think of are those in diatomic molecules of gases. In every other case electronegativity of the atoms is different and the bond has some ionic character and some covalent character.

Please note covalent/ionic classification is not precise - while there are obvious differences between bonds (compounds) on both ends of the scale, there is a continuum of intermediary states. Where we put the border between one type of the bond and other type of the bond is just a convention.
 
Borek said:
The only purely covalent bonds I can think of are those in diatomic molecules of gases.
Just to add a precision: that would be homonuclear diatomic molecules. You can add also other special cases like the CC bond in ethane, where the molecule is completely symmetric.
 
DrClaude said:
Just to add a precision: that would be homonuclear diatomic molecules.

Good point, thanks. That's what I had on mind, but the wording was lousy.
 
Even homonuclear bonds have an ionic contribution, and it is not easy to quantify the respective portion of covalent vs. ionic bonding. One appealing methods is the Bader analysis of "atoms in molecules":
http://www.chemistry.mcmaster.ca/aim/
 
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