How Is the Ground State Energy of Two Interacting Ions Calculated?

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Homework Help Overview

The discussion revolves around a quantum mechanics problem involving the calculation of the ground state energy of two interacting ions with fixed separation. The interaction Hamiltonian is defined in terms of spin angular momentum operators, and participants are exploring the implications of this setup.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants are attempting to understand the derivation of the ground state energy expression from the given Hamiltonian. There are questions about the equivalence of different answers and the implications of treating spin values as scalars.

Discussion Status

Some participants have provided insights into the problem's context and the mathematical identities involved. There is ongoing exploration of the relationship between the derived expressions and the physical interpretation of the results. Multiple interpretations of the problem are being discussed, particularly regarding the nature of the spin values.

Contextual Notes

Participants note that the problem originates from a practice physics GRE and is not assigned homework. There are reminders about forum rules regarding attempts to solve problems and the nature of assistance provided.

scorinaldi
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Quantum Mechanics Problem. Help!

Hey gang,

This is a physicsGRE problem ( GR9677 question #77 ) that I have yet to see anyone answer well.

Please let me know if I'm not being clear. Here goes:

Question:

"Two ions, 1 and 2, at fixed separation, with spin angular momentum operators S_1 and S_2, have
the interaction Hamiltonian H = -JS_1 (dot) S_2, where J > 0.

The values of (S_1)^2 and (S_2)^2 are fixed at S_1(S_1 + 1) and S_2(S_2 + 1), respectively.
Which of the following is the energy of the ground state of the system?"

Ok, that's the question. The answer is:

-(J/2)[( S_1 + S_2)( S_1 + S_2 + 1) - S_1(S_1 + 1) - S_2(S_2 + 1)]

How did we get this answer? Can someone fill in the steps?
 
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...which is, by the way, simply E= -J*s_1*s_2. You can write this at the start if you see that the most negative energy will be when the spins align with each other and have the largest individual magnitudes in the z-direction (taking the states to be eigenstates of Sz), as in classical dipole problems.
 
A reminder of the rules, to all above, in case you haven't had a chance to read them yet:
https://www.physicsforums.com/showthread.php?t=5374

NOTE: You MUST show that you have attempted to answer your question in order to receive help. You MUST make use of the homework template, which automatically appears when a new topic is created in the homework help forums.

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Thanks, and welcome to PF.
 
Last edited:
a bit of explanation

hi gokul,

this problem was not assigned to me ( or anyone else ) for homework. it is a problem from a practice physics GRE from the 90's where the answers were distributed by ETS.

the distributed packet is here: ( http://phys.columbia.edu/~hbar/Physics-GRE.pdf )

answers and discussion of this particular problem, and all old physics GRE problems are freely available to anyone here: http://grephysics.net/ans/9677/77

i apologize if i posted this in the wrong forum, in that it is not homework. I just wanted to get another insight into ways to arrive at the problem besides the one given on the Physics GRE bulletin boards.

thanks
 
Last edited by a moderator:
scorinaldi said:
hi gokul,

this problem was not assigned to me ( or anyone else ) for homework. it is a problem from a practice physics GRE from the 90's where the answers were distributed by ETS.

the distributed packet is here: ( http://phys.columbia.edu/~hbar/Physics-GRE.pdf )

answers and discussion of this particular problem, and all old physics GRE problems are freely available to anyone here: http://grephysics.net/ans/9677/77

i apologize if i posted this in the wrong forum, in that it is not homework. I just wanted to get another insight into ways to arrive at the problem besides the one given on the Physics GRE bulletin boards.

thanks

It doesn't really matter where the question comes from. When it is the TYPE that involves working out a solution, the rules apply and it belongs on this forum.

Zz.
 
Last edited by a moderator:


scorinaldi said:
Ok, that's the question. The answer is:

-(J/2)[( S_1 + S_2)( S_1 + S_2 + 1) - S_1(S_1 + 1) - S_2(S_2 + 1)]

How did we get this answer? Can someone fill in the steps?

I'm having problems with this question too, even though I've checked the grephysics.net page and this thread at physicsgre.com, not to mention this thread. The issue is that if [tex]S_1[/tex] and [tex]S_2[/tex] are scalars, then when you carry out the multiplication this answer (D) is identical to answer B, which is [tex]-J S_1 S_2[/tex], and we can't have two identical answers.

Here's some work, borrowing heavily from the grephysics.net site:

We start with:
[tex]H = -J \bold{S_1} \cdot \bold{S_2}[/tex]
Using the identity
[tex]\bold{a} \cdot \bold{b} = \frac{1}{2} ( (\bold{a} + \bold{b})^2 - a^2 - b^2 )[/tex]
we get
[tex]H = - \frac{J}{2} ( (\bold{S_1} + \bold{S_2})^2 - (S_1)^2 - (S_2)^2 )[/tex]

Now, [tex](S_1)^2 \psi = s_1 (s_1 + 1) \psi[/tex], and the same goes for [tex]S_2[/tex], where I use lowercase s for eigenvalues, a non-bold uppercase S for non-vector operators, and a bold uppercase [tex]\bold{S}[/tex] for vector operators. We now have

[tex]H = - \frac{J}{2} ( (\bold{S_1} + \bold{S_2})^2 - s_1 (s_1 + 1) - s_2 (s_2 + 1))[/tex]

Finally, a comment on the physicsgre.net site says that
[tex](\bold{S_1} + \bold{S_2})^2[/tex]
becomes
[tex](s_1 + s_2) (s_1 + s_2 + 1)[/tex]
and thus we get answer D. (I don't understand this step too well.) But the problem is, as I've stated above, if the S_1 and S_2 values are scalars, then answer B and answer D are identical. The answer is supposed to be an energy, rather than a Hamiltonian. Is the problem wrong or are answers B and D supposed to be different?
 


I don't have access to the full question, but here's what I gather:

first, the problem is clearly about how to add two angular momenta. The answer D is indeed correct: the total angular momentum of the two systems together lies between
two values (look them up in your textbook!), and the maximum possible value gives rise to the lowest energy.

second, if answer B is in fact what it is claimed to be here (as I said, I haven't seen the full question) then that is the same answer. So, someone screwed up the question in that case.
 

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