Calculating Freezing and Boiling Points

AI Thread Summary
To calculate the freezing and boiling points of solutions like 0.070 m MgCl2 and 0.020 m FeCl3, the van't Hoff factor (i) is essential, as it affects the change in temperature (ΔT). The equations ΔTf = freezing point of pure solvent - new freezing point and ΔTb = new boiling point - boiling point of pure solvent are used to determine the new temperatures. The value of K, which is specific to each solvent, must be referenced from textbooks or reliable online sources. The calculations require knowing the initial boiling and freezing points of the pure solvent, as well as the molality of the solutions. Accurate results depend on correctly applying these formulas and values.
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Homework Statement


Calculate the freezing point and boiling point of each of the following solutions using the observed van't Hoff factors in Table 11.6.

(a) 0.070 m MgCl2
Temp Freezing?

Temp Boiling?


(b) 0.020 m FeCl3
Temp Freezing?

Temp Boiling?



Homework Equations


Change in T= imK
i=Van't Hoff factor
m=given
K=freezing point depression or boiling point elevation


The Attempt at a Solution


I don't know what the change in temp is so I can't solve for K.
Tf MgCl2- Change in T= (3)(.07)K Don't know K or T
 
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∆Tb=New boiling point-Boiling point of pure solvent
∆Tf=Freezing point of pure solvent-New freezing point,
now knowing boiling/freezing point of the pure solvent, i, m and K(which will be given) you can find the new boiling/ freezing point.
 
K is a property of the solvent. It has a specific value for every solvent, and can be looked up in your textbook, or a handbook, or on the web.

See the tables on this page: http://dbhs.wvusd.k12.ca.us/webdocs/Solutions/BP-Elev-and-FP-Lower.html
 
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