WhoWee said:
I'm trying to convert an old 12 Volt car battery into an HHO generator. I want to achieve electrolysis of water using a dead battery as the vessel. A battery seems to have all of the necessary components: water tight case, electrodes, connections, and vent holes.
I've witnessed other devices that achieve electrolysis (using titanium and stainless electrodes and a little baking soda) and then hold a small charge...so I figured "why build a battery...why not use a battery?
Unlike everyone else doing this, I'm not trying to fuel a motor or improve gas mileage. Instead, I want to generate a small quantity of HHO on demand, run it through a 1/8 plastic tube and try to achieve/test a small flame with a very clean burn (ultimately for use in a very light manufacturing process).
Phrak has provided sound information. Respectfully, please read this slowly and give it plenty of open-minded thought. You aren't the first to want to use a lead-acid battery in this manner and likely won't be the last.
I understand that you’ve removed the normal electrolyte and have neutralized the battery and that it’s not being used as normally intended. However, you are missing a very important detail.
A lead-acid battery is assembled in a manner that has interwoven plates per each of its 6 cells and this of course, is how each cell develops its 2.1 ~2.2 volts and THIS is where the problem begins per YOUR intended usage.
Regardless of the water and manner of salt used to make the water conduct current for electrolysis purposes, EACH of the interwoven plates will develop a small voltage drop per Kirchhoff’s law. In doing so, the alternate sides of each plate will develop both a negative polarity (producing the fuel, hydrogen) and a positive polarity (producing the oxidizer, oxygen). Therefore, per EACH of the 6 cells, a highly explosive mixture of hydrogen AND oxygen will be produced and already premixed prior to your usage. In these portions, it does NOT allow for a controlled burn. It will simply explode the instant that it is ignited because the oxidizer is already combined with the fuel, so there's no means to meter oxygen intake to the fuel (HH).
This is why batteries are fully capable of blowing up (and I know several guys who found this out the hard way, including my own younger brother) if sparks and prevailing winds allow the gases emitted during battery charging to be ignited. (My brother lived and is o.k., but he did not forget the lesson that he learned the hard way. Now batteries give him the jeebies. Good! LOL)
In a normal electrolysis set up, there is only one positive electrode and one negative electrode and they are separated via the electrolyte. Since this configuration has no multiple interwoven plates, each electrode’s surface area remains at its greatest positive and the other at its greatest negative potential therefore, no positive and negative per alternate sides of the same electrode. This allows the hydrogen and oxygen to be produced exclusively per each electrode (neg, HH, Pos, O), as well as collected separately and safely.
Unfortunately, the lead-acid battery assembled with its interwoven plates makes it essentially useless for your intended purpose.