Creating a 50% Citric Acid Solution: Step-by-Step Guide

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To create a 50% citric acid solution, it is essential to dissolve 50 grams of solid citric acid in enough water to achieve a final volume of 100 mL, rather than simply adding 50 grams to 100 mL of water. This distinction is crucial, as the latter method would result in a solution that is approximately 40% w/v due to the volume occupied by the citric acid itself. Proper preparation involves adding the solid citric acid first and then adding water until the total volume reaches 100 mL.
tonibalt
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how can I make a 50% citric acid solution?
 
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tonibalt said:
how can I make a 50% citric acid solution?

Assuming a w/v % solution, you would dissolve 50g solid citric acid in 100ml H2O.

Question should technically go in the HWK section though.
 
~christina~ said:
Assuming a w/v % solution, you would dissolve 50g solid citric acid in 100ml H2O.

No, you should dissolve 50g of citric acid in such an amount of water that final volume is 100 mL. That's not the same. For diluted solutions - like 2 or 4 % w/v difference is small, but in the case of 50% w/v prepared your way you will get solution that will be in reality about 40% w/v.

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thanks for reponses
 
Borek said:
No, you should dissolve 50g of citric acid in such an amount of water that final volume is 100 mL. That's not the same. For diluted solutions - like 2 or 4 % w/v difference is small, but in the case of 50% w/v prepared your way you will get solution that will be in reality about 40% w/v.

Thanks Borek
:redface: What I posted before would not make any sense when I think about it. (If I was making the solution in the lab I would add solid and then add water to the 100ml mark of vol flask) Thus it is not 100ml that I would be adding to make the solution.
 
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