PAllen
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The most common derivations go about this in different order (which does not imply the above is incorrect). You first note or derive that any metric can be put in synchronous form (for some finite region). Then, argue that isotropy everywhere (which implied homogeneity) puts the space-space metric components in one of 3 forms, each diagonal only (for hyperbolic, flat, or positive curvature spatial slices). Then, argue that the coordinate coverage is global (also due to isotropy/homogeneity). This is basically how Weinberg goes about it, for example.PeterDonis said:Actually, one can state the assumption in a way that does not depend on any choice of coordinates. The assumption, stated in an invariant way, is that the spacetime can be foliated by spacelike 3-surfaces that are all homogeneous and isotropic. This of course implies that one can choose a coordinate chart in which each such 3-surface is a surface of constant coordinate time.
I believe that the existence of a family of timelike worldlines that is orthogonal to the above spacelike 3-surfaces can also be derived from the above assumption. This then implies that the metric in above coordinate chart has the general FRW form.
However, you are trying to get away from coordinates, as much as possible. Since the only assumption above that is unique to FRW is the isotropy/homogeneity, it suggests it should be possible to turn the arguments around as you suggest; I've just never seen it done 'rigorously' in that order.
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