Calculate the voltage of a standard cell with the following half-cell reactions

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Discussion Overview

The discussion revolves around calculating the voltage of a standard cell based on given half-cell reactions involving nickel and chlorine, as well as related questions about charge and time in the context of electrolysis of water.

Discussion Character

  • Homework-related
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant presents half-cell reactions for nickel and chlorine and asks for help in calculating the voltage of a standard cell.
  • Another participant questions the need for help, suggesting that the questions are standard and should be solvable independently.
  • A participant expresses unfamiliarity with calculating voltage and charge, seeking hints rather than direct answers.
  • One reply suggests that the original poster should refer to Faraday's Laws of Electrolysis for guidance.
  • Hints are provided regarding the relationship between the standard emf values of half reactions and the stoichiometric ratios of electrons involved.
  • Further hints encourage the participant to convert the volume of oxygen produced into moles to assist in solving the charge and time questions.

Areas of Agreement / Disagreement

There is no consensus on the approach to solving the problem, as participants express varying levels of familiarity and comfort with the material. Some participants offer hints while others challenge the need for assistance.

Contextual Notes

Participants reference concepts such as Faraday's Laws and stoichiometric relationships, but there is no agreement on specific methods or calculations. The discussion does not resolve the calculations or provide definitive guidance.

Who May Find This Useful

Students or individuals seeking assistance with electrochemistry concepts, particularly those related to standard cell voltage calculations and electrolysis.

BH20
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1. I have to calculate the voltage of a standard cell with the following half-cell reactions:

Ni(s) ---> Ni2+ + 2e-
2e- + Cl2(g) ---> 2Cl-

2. By the electrolysis of water, 11.2L of oxygen at STP was prepared
a) What charge was required?
b) If a current of 0.5A was used, how long did it take?

Thanks for the help.
 
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what do you need help for? these are all standard questions, it doesn't get any easier then this. Try solving it yourself first, show your work.
 
these questions may very well be easy for you..but I am not familiar with calculating voltage and charge.

I don't need the answer, just a helpful hint. (a site, or something..I don't mind doing the work but I don't see any useful info about it in my book)
 
Last edited:
I'm sure your text talks about Faraday's Laws of Electrolysis. If not :eek:, there's always Google.
 
hint #1

finding the voltage of the standard cell is similar to Hess' law (with the emphasis on "similar"). Perhaps you can remember the method now. What can you do with each of the standard emf values for each half reaction to solve the problem? The question is especially easy since the stoichiometric ratio of electrons are the same.

hint #2

2. By the electrolysis of water, 11.2L of oxygen at STP was prepared
a) What charge was required?
b) If a current of 0.5A was used, how long did it take?

It is quite important that you read up on this subject, it should be at the end of the electrolysis section of your text. First, what can yo do with the 11.2L at STP, how can yo convert this to moles?
 

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