To calculate the concentration of Ba(OH)2 from the titration with H2SO4, first determine the normality of the H2SO4 solution, which is 0.204 N. Use the neutralization equation N1V1 = N2V2, where N1 is the normality of H2SO4 and V1 is its volume, to find the normality of Ba(OH)2. After calculating, divide the result by 2 to obtain the molarity of Ba(OH)2. Alternatively, calculate moles directly using the molarity of H2SO4 and its volume, then set up a molarity equation for Ba(OH)2. This approach provides the necessary tools to find the concentration effectively.