The discussion centers on calculating the mass of oxygen in 250g of CaCO3, with an initial incorrect assumption that the mass of oxygen could be derived by dividing the total mass by the number of oxygen atoms. The correct calculation involves determining the fraction of the mass that is oxygen, which is approximately 0.4796, leading to a mass of 119.9g of oxygen in 250g of CaCO3. Two methods are presented: one using the mass fraction and the other calculating moles of CaCO3 and multiplying by the number of oxygen atoms per molecule. The participants conclude that the original method was flawed due to misunderstanding the relationship between the total mass and the constituent elements. The final confirmed mass of oxygen in the compound is 119.9g.